Ionic Re(I) complexes with 4-(4-triphenylsilanylphenyl) pyridine: Synthesis, characterization, sensoring properties and DFT calculations

被引：3
作者：
Chen, Cong [1 ,2 ]
Zuo, Qinghui [2 ]
Wan, Yuchun [2 ]
Si, Zhenjun [2 ]
Duan, Qian [2 ]
机构：
[1] Qinghai Univ Nationalities, Coll Phys & Elect Informat Engn, 3 Bayizhonglu, Xining 810007, Peoples R China
[2] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, 7989 Waxing Rd, Changchun 130022, Peoples R China
来源：
JOURNAL OF LUMINESCENCE | 2017年 / 184卷
关键词：
RHENIUM(I) COMPLEX; EMISSIVE BEHAVIOR; CRYSTAL-STRUCTURE; LUMINESCENCE; PROBES;
D O I：
10.1016/j.jlumin.2016.12.044
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
4-(4-triphenylsilanylphenyl) pyridine(TPhSiPy)was synthesized and used to prepare three ionic Re(I)complexesof[Re(CO) 3 (NN)(TPhSiPy)]CF3SO3, where NN was 2,2’-bipyridine(bpy)for 1, 1,10-phenanthroline(phen)for 2, and bathophenanthroline for 3. The photophysical properties and the electrochemical properties and the optical sensering properties of 1∼3 were also systematically investigated. The UV–Vis absorption spectra and photoluminescence (PL) spectra were measured on a Perkin Elmer Lambda 950 Spectrophotometer and Perki-nElmer LS-55 Spectrophotometer. The PL quantum yields (PLQYs) were determined on 10-5 mol/L tetrahydrofuran (THF) solution according to a given equation.
引用
收藏
页码：242 / 249
页数：8
相关论文
共 40 条
[1]   Rhenium fac tricarbonyl bisimine complexes:: biologically useful fluorochromes for cell imaging applications [J].
Amoroso, Angelo J. ;
Coogan, Michael P. ;
Dunne, Jennifer E. ;
Fernandez-Moreira, Vanesa ;
Hess, Jacob B. ;
Hayes, Anthony J. ;
Lloyd, David ;
Millet, Coralie ;
Pope, Simon J. A. ;
Williams, Craig .
CHEMICAL COMMUNICATIONS, 2007, (29) :3066-3068
[2]   Influence of substituents on the energy and nature of the lowest excited states of heteroleptic phosphorescent Ir(III) complexes: A joint theoretical and experimental study [J].
Avilov, Igor ;
Minoofar, Payam ;
Cornil, Jerome ;
De Cola, Luisa .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8247-8258
[3]   Femtosecond fluorescence and intersystem crossing in rhenium(I) carbonyl-bipyridine complexes [J].
Cannizzo, Andrea ;
Blanco-Rodriguez, Ana Maria ;
El Nahhas, Amal ;
Sebera, Jakub ;
Zalis, Stanislav ;
Vlcek, Antonin, Jr. ;
Chergui, Majed .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (28) :8967-8974
[4]   Aggregation-Induced Phosphorescent Emission from ReI Complexes: Synthesis and Property Studies [J].
Chen, Cong ;
Xu, Yazhou ;
Wan, Yuchun ;
Fan, Wei ;
Si, Zhenjun .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (09) :1340-1347
[5]   EFFECTS OF CONFORMATIONAL CHANGE IN THE ACCEPTOR ON INTRAMOLECULAR ELECTRON-TRANSFER [J].
CHEN, PY ;
CURRY, M ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1989, 28 (12) :2271-2280
[6]   Rhenium(I) polypyridine dibenzocyclooctyne complexes as phosphorescent bioorthogonal probes: Synthesis, characterization, emissive behavior, and biolabeling properties [J].
Choi, Alex Wing-Tat ;
Liu, Hua-Wei ;
Lo, Kenneth Kam-Wing .
JOURNAL OF INORGANIC BIOCHEMISTRY, 2015, 148 :2-10
[7]   Rhenium(I) Polypyridine Diamine Complexes as Intracellular Phosphorogenic Sensors: Synthesis, Characterization, Emissive Behavior, Biological Properties, and Nitric Oxide Sensing [J].
Choi, Alex Wing-Tat ;
Yim, Vicki Man-Wai ;
Liu, Hua-Wei ;
Lo, Kenneth Kam-Wing .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (31) :9633-9642
[8]   Rhenium(I) polypyridine complexes functionalized with a diaminoaromatic moiety as phosphorescent sensors for nitric oxide [J].
Choi, Alex Wing-Tat ;
Poon, Che-Shan ;
Liu, Hua-Wei ;
Cheng, Heung-Kiu ;
Lo, Kenneth Kam-Wing .
NEW JOURNAL OF CHEMISTRY, 2013, 37 (06) :1711-1719
[9]   Endowing hexaphenylsilole with chemical sensory and biological probing properties by attaching amino pendants to the silolyl core [J].
Dong, Yongqiang ;
Lam, Jacky W. Y. ;
Qin, Anjun ;
Li, Zhen ;
Liu, Jianzhao ;
Sun, Jingzhi ;
Dong, Yuping ;
Tang, Ben Zhong .
CHEMICAL PHYSICS LETTERS, 2007, 446 (1-3) :124-127
[10]  
Frisch MJ, 2013, Gaussian 09
1234