Alkane oxygenation with hydrogen peroxide catalysed by soluble derivatives of nickel and platinum

被引：23

作者：

Shul'pin, GB ^{[1
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2002年 / 07期

关键词：

alkanes; catalysis; hydrogen peroxide; nickel; platinum;

D O I：

10.3184/030823402103172257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various alkanes can be oxidised by hydrogen peroxide in acetonitrile solution at 70degreesC if Ni(ClO4)(2) (in the presence of 1,4,7-trimethyl-1,4,7-triazacyclononane) or H2PtCl6 are used as catalysts; whereas the nickel-catalysed reaction seems to proceed via attack of hydroxyl radicals on an alkane, the oxidation in the presence of platinum occurs possibly with participation of oxo or peroxo derivatives of this metal.

引用

页码：351 / 353

页数：3

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