Direct synthesis of high-quality graphene on Cu powders from adsorption of small aromatic hydrocarbons: A route to high strength and electrical conductivity for graphene/Cu composite

被引：66

作者：

Wang, Miao ^{[1
]}

Wang, Li-Dong ^{[1
]}

Sheng, Jie ^{[1
]}

Yang, Zi-Yue ^{[1
]}

Shi, Zhen-Dong ^{[1
]}

Zhu, Yun-Peng ^{[3
]}

Li, Jie ^{[1
]}

Fei, Wei-Dong ^{[1
,2
]}

机构：

[1] Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Heilongjiang, Peoples R China

[2] Harbin Inst Technol, State Key Lab Adv Welding & Joining, Harbin 150001, Heilongjiang, Peoples R China

[3] Qinghai Univ, Sch Mech Engn, Xining 810016, Qinghai, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2019年 / 798卷

基金：

中国国家自然科学基金;

关键词：

Graphene/Cu composites; Scalable synthesis; High strength; High electrical conductivity; ENHANCED MECHANICAL-PROPERTIES; COPPER MATRIX COMPOSITES; REINFORCED METAL; INTERFACE; GROWTH; MICROSTRUCTURE; FILMS; NANOCOMPOSITES; NANOPARTICLES; FABRICATION;

D O I：

10.1016/j.jallcom.2019.05.273

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A low-cost and easily-accessible approach based on adsorption of small aromatic hydrocarbons (SAHs) was developed to synthesize graphene on Cu powders, which could supply raw material for powder metallurgy (PM) fabrication of graphene/Cu composites. Two common SAHs, naphthalene and alpha-naphthol, were chosen as the carbon precursors. Compared with naphthalene, it was found that the hydroxyl group in alpha-naphthol could be chemically adsorbed on Cu powders, which could not only be effective in preventing Cu powders from agglomerating together at high temperature but also promote the growth of high-quality graphene. Therefore, alpha-naphthol-derived graphene on Cu powders were chosen to fabricate graphene/Cu composites by spark plasma sintering and hot-rolling. The composites exhibited a microstructure with extremely homogeneous dispersion of graphene, exceptional high strength and simultaneously similar electrical conductivity compared with that of the matrix. Cu-O-C bond was found and could improve the interfacial bonding between graphene and matrix. Experimental and theoretical calculation results revealed that the load transfer, grain refinement and thermal mismatch mechanism provided by graphene were the main strengthening mechanism in the composite. This synthetic procedure is quite scalable for industrial use to fabricate graphene/Cu composites with high performance. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：403 / 413

页数：11

共 56 条

[1] Gold nanorods as nanoadmicelles: 1-naphthol partitioning into a nanorod-bound surfactant bilayer [J].

Alkilany, Alaaldin M. ;

Frey, Rebecca L. ;

Ferry, John L. ;

Murphy, Catherine J. .

LANGMUIR, 2008, 24 (18) :10235-10239

[2] Aligning graphene in bulk copper: Nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity [J].

Cao, Mu ;

Xiong, Ding-Bang ;

Tan, Zhanqiu ;

Ji, Gang ;

Amin-Ahmadi, Behnam ;

Guo, Qiang ;

Fan, Genlian ;

Guo, Cuiping ;

Li, Zhiqiang ;

Zhang, Di .

CARBON, 2017, 117 :65-74

[3] Metal Matrix Composites Reinforced by Nano-Particles-A Review [J].

Casati, Riccardo ;

Vedani, Maurizio .

METALS, 2014, 4 (01) :65-83

[4] Fabrication of in-situ grown graphene reinforced Cu matrix composites [J].

Chen, Yakun ;

Zhang, Xiang ;

Liu, Enzuo ;

He, Chunnian ;

Shi, Chunsheng ;

Li, Jiajun ;

Nash, Philip ;

Zhao, Naiqin .

SCIENTIFIC REPORTS, 2016, 6

[5] Drastic reduction in the growth temperature of graphene on copper via enhanced London dispersion force [J].

Choi, Jin-Ho ;

Li, Zhancheng ;

Cui, Ping ;

Fan, Xiaodong ;

Zhang, Hui ;

Zeng, Changgan ;

Zhang, Zhenyu .

SCIENTIFIC REPORTS, 2013, 3

[6] Graphene defect engineering for optimizing the interface and mechanical properties of graphene/copper composites [J].

Chu, Ke ;

Wang, Jing ;

Liu, Ya-ping ;

Geng, Zhong-rong .

CARBON, 2018, 140 :112-123

[7] Interface and mechanical/thermal properties of graphene/copper composite with Mo2C nanoparticles grown on graphene [J].

Chu, Ke ;

Wang, Fan ;

Li, Yu-biao ;

Wang, Xiao-hu ;

Huang, Da-jian ;

Geng, Zhong-rong .

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2018, 109 :267-279

[8] Enhanced strength in bulk graphene-copper composites [J].

Chu, Ke ;

Jia, Chengchang .

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2014, 211 (01) :184-190

[9] Electrical and mechanical properties of carbon nanotube reinforced copper nanocomposites fabricated by electroless deposition process [J].

Daoush, Walid M. ;

Lim, Byung K. ;

Mo, Chan B. ;

Nam, Dong H. ;

Hong, Soon H. .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2009, 513-14 :247-253

[10] Microstructure and properties of bulk copper matrix composites strengthened with various kinds of graphene nanoplatelets [J].

Dutkiewicz, Jan ;

Ozga, Piotr ;

Maziarz, Wojciech ;

Pstrus, Janusz ;

Kania, Bogusz ;

Bobrowski, Piotr ;

Stolarska, Justyna .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2015, 628 :124-134

← 1 2 3 4 5 6 →