Magnetic Bistability of Individual Single-Molecule Magnets Grafted on Single-Wall Carbon Nanotubes

被引:89
作者
Giusti, Anna [1 ]
Charron, Gaelle [1 ]
Mazerat, Sandra [1 ]
Compain, Jean-Daniel [2 ]
Mialane, Pierre [2 ]
Dolbecq, Anne [2 ]
Riviere, Eric [1 ]
Wernsdorfer, Wolfgang [3 ]
Bibouni, Rosa Ngo [4 ]
Keita, Bineta [4 ]
Nadjo, Louis [4 ]
Filoramo, Arianna [5 ]
Bourgoin, Jean-Philippe [5 ]
Mallah, Talal [1 ]
机构
[1] Univ Paris 11, CNRS, Inst Chim Mol & Mat Orsay, UMR 8182, F-91405 Orsay, France
[2] Inst Lavoisier Versailles, Versailles, France
[3] Inst Neel, Grenoble, France
[4] Chim Phys Lab, Orsay, France
[5] CNRS, Lab Elect Mol, Gif Sur Yvette, France
关键词
iron; magnetic properties; nanotubes; polyoxometalates; single-molecule magnets; RAMAN-SPECTROSCOPY; SURFACE; GOLD;
D O I
10.1002/anie.200901806
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A POM to remember: Hexanuclear FeIII polyoxometalate (POM) single-molecule magnets (see structure) can be noncovalently assembled on the surface of single-wall carbon nanotubes. Complementary characterization techniques (see TEM image and magnetic hysteresis loops) demonstrate the integrity and bistability of the individual molecules, which could be used to construct single-molecule memory devices. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4949 / 4952
页数:4
相关论文
共 21 条
[1]  
[Anonymous], 2009, ANGEW CHEM
[2]  
Bogani L., 2009, ANGEW CHEM, V121, P760
[3]   A perspective on combining molecular nanomagnets and carbon nanotube electronics [J].
Bogani, Lapo ;
Wernsdorfer, W. .
INORGANICA CHIMICA ACTA, 2008, 361 (14-15) :3807-3819
[4]   Molecular spintronics using single-molecule magnets [J].
Bogani, Lapo ;
Wernsdorfer, Wolfgang .
NATURE MATERIALS, 2008, 7 (03) :179-186
[5]   Single-Molecule-Magnet Carbon-Nanotube Hybrids [J].
Bogani, Lapo ;
Danieli, Chiara ;
Biavardi, Elisa ;
Bendiab, Nedjnta ;
Barra, Anne-Laure ;
Dalcanale, Enrico ;
Wernsdorfer, Wolfgang ;
Cornia, Andrea .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (04) :746-750
[6]   Insights into the mechanism of the gas-phase purification of HiPco SWNTs through a comprehensive multi-technique study [J].
Charron, Gaelle ;
Mazerat, Sandra ;
Erdogan, Mehmet ;
Gloter, Alexandre ;
Filoramo, Arianna ;
Cambedouzou, Julien ;
Launois, Pascale ;
Riviere, Eric ;
Wernsdorfer, Wolfgang ;
Bourgoin, Jean-Philippe ;
Mallah, Talal .
NEW JOURNAL OF CHEMISTRY, 2009, 33 (06) :1211-1223
[7]   Purification and characterization of single-wall carbon nanotubes (SWNTs) obtained from the gas-phase decomposition of CO (HiPco process) [J].
Chiang, IW ;
Brinson, BE ;
Huang, AY ;
Willis, PA ;
Bronikowski, MJ ;
Margrave, JL ;
Smalley, RE ;
Hauge, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (35) :8297-8301
[8]   Iron Polyoxometalate Single-Molecule Magnets [J].
Compain, Jean-Daniel ;
Mialane, Pierre ;
Dolbecq, Anne ;
Mbomekalle, Israel Martyr ;
Marrot, Jerome ;
Secheresse, Francis ;
Riviere, Eric ;
Rogez, Guillaume ;
Wernsdorfer, Wolfgang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (17) :3077-3081
[9]   Raman spectroscopy of carbon nanotubes in 1997 and 2007 [J].
Dresselhaus, M. S. ;
Dresselhaus, G. ;
Jorio, A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (48) :17887-17893
[10]   Raman spectroscopy of carbon nanotubes [J].
Dresselhaus, MS ;
Dresselhaus, G ;
Saito, R ;
Jorio, A .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 2005, 409 (02) :47-99