Crystal structure of CF3TeTeCF3. Synthesis, characterization, and properties of CF3TeI

被引：20

作者：

Dukat, W ^{[1
]}

Gall, F ^{[1
]}

Meyer, C ^{[1
]}

Mootz, D ^{[1
]}

Naumann, D ^{[1
]}

Nowicki, G ^{[1
]}

Schultz, K ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ANORGAN CHEM,D-50939 COLOGNE,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 04期

关键词：

trifluoromethyl tellurium compounds; crystal structure; NMR spectra; metathesis reactions;

D O I：

10.1002/zaac.19966220407

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Te-2(CF3)(2) crystallizes in the monoclinic space group P2(1)/a with four formular units in the unit cell. The lattice constants are a = 10.13(1) Angstrom, b = 11.489(7) Angstrom, c = 6.822(8) Angstrom and beta = 101.20(8)degrees. CF3TeI is prepared by a quantitative reaction of Te-2(CF3)(2) With equimolar amounts of iodine. This compound is very instable, no isolation is possible. NMR spectra have been registrated. From metathesis reactions CF(3)TeX (X = C=CC6H5, t-C4H9, SCN, SC6F5) are prepared.

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页码：617 / 621

页数：5

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