Metal-phenolic networks as a versatile platform to engineer nanomaterials and biointerfaces

被引：495

作者：

Ejima, Hirotaka ^{[2
]}

Richardson, Joseph J. ^{[3
]}

Caruso, Frank ^{[1
]}

机构：

[1] Univ Melbourne, ARC Ctr Excellence Convergent Bionano Sci & Techn, Parkville, Vic 3010, Australia

[2] Univ Tokyo, Sch Engn, Dept Mat Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan

[3] CSIRO Mfg, CSIRO Private Bag 10, Clayton, Vic 3169, Australia

来源：

NANO TODAY | 2017年 / 12卷

基金：

澳大利亚研究理事会;

关键词：

Metal-phenolic networks (MPNs); Self-assembly; Polyphenols; Organic-inorganic hybrid materials; Surface functionalization; INDIVIDUAL MAMMALIAN-CELLS; BY-LAYER DEPOSITION; TANNIC-ACID; POLYPHENOL CHEMISTRY; GRAPHENE OXIDE; PH; CAPSULES; NANOPARTICLES; FILMS; COATINGS;

D O I：

10.1016/j.nantod.2016.12.012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Surface modification is crucial for conferring novel functionalities to objects and interfaces. However, simple yet versatile strategies for the surface modification of multiple classes of nanomaterials, including biointerfaces, are rare, as the chemical interactions between the surface modifiers and the substrates need to be tailored on a case-by-case basis. Recently, metal-phenolic networks (MPNs) have emerged as a versatile surface modifier based on the universal adherent properties of phenolic molecules, namely the constituent gallol and catechol groups. Additionally, the dynamic interactions between metal ions and phenolic molecules confer additional functionalities to the MPNs, such as stimuli-responsiveness. Given the interest in MPNs for nanomaterial and biointerface engineering, this review aims to provide an overview of the assembly process, physicochemical properties and applications of MPN coatings. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：136 / 148

页数：13

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