Electronic nose based on metal oxide semiconductor sensors as a fast alternative for the detection of adulteration of virgin olive oils

被引:118
作者
Oliveros, MCC
Pavón, JLP
Pinto, CG
Laespada, MEF
Cordero, BM
Forina, M
机构
[1] Univ Salamanca, Fac Ciencias Quim, Dept Quim Anal Nutr & Bromatol, Salamanca 37008, Spain
[2] Univ Genoa, Dipartimento Chim & Tecnol Farmaceut & Alimentari, I-16147 Genoa, Italy
关键词
electronic olfactometry; metal oxide semiconductor gas sensors; supervised pattern recognition techniques; virgin olive oils; adulteration;
D O I
10.1016/S0003-2670(02)00119-8
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An "electronic nose" has been used for the detection of adulterations of virgin olive oil. The system, comprising 12 metal oxide semiconductor sensors, was used to generate a pattern of the volatile compounds present in the samples. Prior to different supervised pattern recognition treatments, feature selection techniques were employed to choose a set of optimally discriminant variables. Linear discriminant analysis (LDA), quadratic discriminant analysis (QDA) and artificial neural networks (ANN) were applied. Excellent results were obtained in the differentiation of adulterated and non-adulterated olive oils and it was even possible to identify the type of oil used in the adulteration. Promising results were also obtained as regards quantification of the percentages of adulteration. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:219 / 228
页数:10
相关论文
共 42 条
[1]  
*ALPH MOS, 1996, FOX 3000 EL NOS OP M
[2]   EVALUATION OF THE BELLIER TEST IN THE DETECTION OF OLIVE OIL ADULTERATION WITH VEGETABLE-OILS [J].
AMR, AS ;
ABUALRUB, AI .
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, 1993, 61 (04) :435-437
[3]  
Angerosa F, 1996, J SCI FOOD AGR, V72, P323, DOI 10.1002/(SICI)1097-0010(199611)72:3<323::AID-JSFA662>3.0.CO
[4]  
2-A
[5]   Carbon stable isotopes and olive oil adulteration with pomace oil [J].
Angerosa, F ;
Camera, L ;
Cumitini, S ;
Gleixner, G ;
Reniero, F .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (08) :3044-3048
[6]   Authentication of vegetable oils by chromatographic techniques [J].
Aparicio, R ;
Aparicio-Ruíz, R .
JOURNAL OF CHROMATOGRAPHY A, 2000, 881 (1-2) :93-104
[7]   Detection of rancid defect in virgin olive oil by the electronic nose [J].
Aparicio, R ;
Rocha, SM ;
Delgadillo, I ;
Morales, MT .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2000, 48 (03) :853-860
[8]   Detection of virgin olive oil adulteration by Fourier transform Raman spectroscopy [J].
Baeten, V ;
Meurens, M ;
Morales, MT ;
Aparicio, R .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1996, 44 (08) :2225-2230
[9]  
Bartlett PN, 1997, FOOD TECHNOL-CHICAGO, V51, P44
[10]  
Casadei E., 1987, Rivista Italiana delle Sostanze Grasse, V64, P373