Polymer electrolyte electrolysis: A review of the activity and stability of non-precious metal hydrogen evolution reaction and oxygen evolution reaction catalysts

被引：133
作者：
Hughes, J. P. [1 ,2 ]
Clipsham, J. [3 ]
Chavushoglu, H. [1 ,2 ]
Rowley-Neale, S. J. [1 ,2 ]
Banks, C. E. [1 ,2 ]
机构：
[1] Manchester Metropolitan Univ, Fac Sci & Engn, Chester St, Manchester M1 5GD, Lancs, England
[2] Manchester Metropolitan Univ, Manchester Fuel Cell Innovat Ctr, Chester St, Manchester M1 5GD, Lancs, England
[3] European Marine Energy Ctr, ORIC, Charles Clouston Bldg,Back Rd, Orkney KW16 3AW, England
来源：
RENEWABLE & SUSTAINABLE ENERGY REVIEWS | 2021年 / 139卷
基金：
英国工程与自然科学研究理事会; “创新英国”项目;
关键词：
Energy storage; PEM Electrolyser; Hydrogen evolution reaction; Renewable energy; Oxygen evolution reaction; Water splitting; SCREEN-PRINTED ELECTRODES; SB-DOPED SNO2; PEM WATER ELECTROLYZERS; HIGHLY-EFFICIENT; BIFUNCTIONAL ELECTROCATALYST; SULFURIC-ACID; CORROSION-RESISTANCE; DEGRADATION ISSUES; ORGANIC FRAMEWORKS; MOS2; NANOPARTICLES;
D O I：
10.1016/j.rser.2021.110709
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The potential for generating green hydrogen by electrolysis (water splitting) has resulted in a substantial amount of literature focusing on lowering the current production cost of hydrogen. A significant contributor to this high cost is the requirement for precious metals (namely Pt and Ir/Ru (oxides)) to catalyse the two main reactions involved in electrolysis: the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Herein we overview the current literature of non-precious metal HER and OER catalysts capable of efficient water splitting within a polymer electrolyte membrane (PEM) electrolyser, recording the activity and stability of each catalyst and allowing for direct comparison to be made. Additionally, we highlight the inapplicability of catalyst stability testing in many academic studies for commercial electrolyser applications and propose a universal stability-testing regime for HER and OER catalysts that more accurately mimics the conditions within an operating electrolyser.
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页数：17
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