Six-Membered Aromatic Polyazides: Synthesis and Application

被引:27
作者
Chapyshev, Sergei V. [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
关键词
polyazides; high-energy materials; high-spin nitrenes; cross-linking agents; photoresists; click-reactions; MAGNETIC-ANISOTROPY PARAMETERS; LOW-TEMPERATURE RADIOLYSIS; HIGH-SPIN NITRENES; MATRIX-ISOLATION; AZIDO GROUPS; QUINTET DINITRENES; NUCLEOPHILIC-SUBSTITUTION; MOLECULAR AZIDE; ORGANIC AZIDES; ANION-BINDING;
D O I
10.3390/molecules201019142
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Aromatic polyazides are widely used as starting materials in organic synthesis and photochemical studies, as well as photoresists in microelectronics and as cross-linking agents in polymer chemistry. Some aromatic polyazides possess high antitumor activity, while many others are of considerable interest as high-energy materials and precursors of high-spin nitrenes and C3N4 carbon nitride nanomaterials. The use of aromatic polyazides in click-reactions may be a new promising direction in the design of various supramolecular systems possessing interesting chemical, physical and biological properties. This review is devoted to the synthesis, properties and applications of six-membered aromatic compounds containing three and more azido groups in the ring.
引用
收藏
页码:19142 / 19171
页数:30
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