Synthesis, characterization, and investigation of catalytic activity of copper(II) porphyrin graphene oxide for azide-alkyne cycloaddition

被引：25

作者：

Khojastehnezhad, Amir ^{[1
]}

Bakavoli, Mehdi ^{[1
]}

Javid, Ali ^{[2
]}

Siuki, Mohammad Mehdi Khakzad ^{[1
]}

Shahidzadeh, Mansour ^{[3
]}

机构：

[1] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad 917751436, Razavi Khorasan, Iran

[2] Islamic Azad Univ, Mashhad Branch, Dept Chem, Mashhad, Razavi Khorasan, Iran

[3] Malek Ashtar Univ Technol, Fac Chem & Chem Engn, Tehran, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2019年 / 45卷 / 09期

基金：

美国国家科学基金会;

关键词：

Porphyrin; Copper; Graphene oxide; 1,2,3-Triazole; Click chemistry; EFFICIENT HETEROGENEOUS CATALYST; HYDROTALCITE;

D O I：

10.1007/s11164-019-03843-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A covalently cross-linked graphene oxide (GO) catalyst was prepared by a cross-linking process using nucleophilic reaction of copper(II)-coordinated 5,10,15,20-tetrakis(aminophenyl)porphyrin (CuPPh) with carboxyl groups at the edges of GO (GO-CuPPh). The structure of the catalyst was characterized using different techniques such as Fourier-transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive x-ray spectroscopy (EDS), thermogravimetric analysis (TGA), and inductively coupled plasma (ICP) spectroscopy. All analyses confirmed successful covalent immobilization of CuPPh on GO. The activity of the catalyst was then studied for synthesis of 1,4-disubstituted 1,2,3-triazoles derivatives by reaction of various aryl azides and different terminal alkynes in mild reaction condition with good to excellent yield. [GRAPHICS] .

引用

页码：4473 / 4485

页数：13

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