Biomorphic SiC-ceramic prepared by Si-vapor phase infiltration of wood

被引:155
作者
Vogli, E [1 ]
Sieber, H [1 ]
Greil, P [1 ]
机构
[1] Univ Erlangen Nurnberg, Dept Mat Sci Glass & Ceram, D-91058 Erlangen, Germany
关键词
biotemplating; mechanical properties; porous ceramics; SiC; Si-vapor infiltration; wood;
D O I
10.1016/S0955-2219(02)00131-0
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The conversion of bioorganie structures like wood or ligninocellulosic fibers into porous microcellular SiC-ceramics is a novel manufacturing technology. Coniferous wood (pine) was transformed by high-temperature pyrolysis into carbon preforms and subsequently converted into biomorphic SiC-ceramics by Si-vapor infiltration under inert atmosphere. The morphology of the initial wood structure is retained. The infiltration of the Si-vapor phase into the CB-template and the kinetics of the SiC-formation were investigated. The amount of residual carbon was determined by means of mass balance calculation. The macroscopical properties of the final SiC-ceramics were characterized by porosity and mechanical property measurements. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2663 / 2668
页数:6
相关论文
共 20 条
[11]   APPRAISAL OF BIAXIAL STRENGTH TESTING [J].
RITTER, JE ;
JAKUS, K ;
BATAKIS, A ;
BANDYOPADHYAY, N .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1980, 38-9 (MAY-) :419-424
[12]  
SHETTY DK, 1980, AM CERAM SOC BULL, V59, P1193
[13]  
Shin DW, 1999, J AM CERAM SOC, V82, P3251, DOI 10.1111/j.1151-2916.1999.tb02234.x
[14]  
Sieber H, 2000, ADV ENG MATER, V2, P105, DOI 10.1002/(SICI)1527-2648(200003)2:3<105::AID-ADEM105>3.0.CO
[15]  
2-P
[16]   CVI-R gas phase processing of porous, biomorphic SiC-ceramics [J].
Sieber, H ;
Vogli, E ;
Müllier, F ;
Greil, P ;
Popovska, N ;
Gerhard, H .
EURO CERAMICS VII, PT 1-3, 2002, 206-2 :2013-2016
[17]   Manufacturing of porous oxide ceramics by replication of plant morphologies [J].
Sieber, H ;
Rambo, C ;
Cao, J ;
Vogli, E ;
Greil, P .
EURO CERAMICS VII, PT 1-3, 2002, 206-2 :2009-2012
[18]  
Vogli E, 2001, J AM CERAM SOC, V84, P1236, DOI 10.1111/j.1151-2916.2001.tb00822.x
[19]   Porous ceramics derived from wood [J].
Vogt, U ;
Herzog, A ;
Graule, T ;
Klingner, R ;
Zimmermann, T .
EURO CERAMICS VII, PT 1-3, 2002, 206-2 :1941-1944
[20]  
ZOLLFRANK C, 2001, ADV CERAMIC MATRIX C, V7