Solvothermal syntheses, structures and properties of two new metal coordination polymers based on rigid 1,3-adamantanedicarboxylic acid ligand

被引：3

作者：

Xia, Jing ^{[1
]}

Su, Zhandong ^{[2
]}

Yang, Lu ^{[1
]}

Zhang, Chenghui ^{[1
]}

Wang, Shuang ^{[1
]}

Shi, Suhua ^{[1
]}

Wang, Li ^{[1
]}

Fan, Yong ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130012, Jilin, Peoples R China

[2] Jilin Univ, Coll Construct Engn, Changchun 130026, Jilin, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2014年 / 418卷

基金：

中国国家自然科学基金;

关键词：

Metal coordination polymer; Crystal structure; 1,3-Adamantanedicarboxylic acid; Ferromagnetism; ORGANIC FRAMEWORKS; COMPLEXES; SORPTION; CHAIN; UNITS;

D O I：

10.1016/j.ica.2014.04.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new metal coordination polymers (CPs) based on rigid 1,3-adamantanedicarboxylic acid (1,3-H(2)adc) ligand have been successfully prepared under different solvothermal conditions. In these two compounds, Ni2Cl2(2,2'-bipy)(2)(1,3-adc) (1) (2,2'-bipy = 2,2'-bipyridine) and Pb(H2O)(1,3-adc) (2), 1,3-adc(2) ligand displays two different coordination modes, constructing disparate architectures by bridging the different building units. Compound 1 features a chiral 1D zigzag chain containing the dimeric [Ni2Cl2 (2,2'-bipy)(2)](2+) units and 1,3-adc(2) bridging ligands. The zigzag chain and its enantiomer alternately stack along the a axis through the pi-pi stacking interactions of bipy ligands. Compound 2 shows a 2D layer with the rhombic windows built from the infinite bent Pb-O chains and 1,3-adc(2) bridging ligands. Moreover, compound 1 shows a high thermal stability limit of 425 degrees C and displays ferromagnetic interactions in the range of 4-300 K. (C) 2014 Elsevier B. V. All rights reserved.

引用

页码：106 / 111

页数：6

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