Passerini addition polymerization of an AB-type monomer - A convenient route to versatile polyesters

被引：38

作者：

Sehlinger, Ansgar ^{[1
]}

Schneider, Rebekka ^{[1
]}

Meier, Michael A. R. ^{[1
]}

机构：

[1] KIT, Inst Organ Chem, Lab Appl Chem, D-76131 Karlsruhe, Germany

来源：

EUROPEAN POLYMER JOURNAL | 2014年 / 50卷

关键词：

Thiol-ene addition; Passerini three-component reaction; Step-growth polymerization; Polyester; Polysulfone; MULTICOMPONENT REACTIONS; 3-COMPONENT REACTION; DRUG DISCOVERY; COPOLYMERS; CHEMISTRY; POLYMERS; CONDENSATION; POLYAMIDES; ALDEHYDES; SEQUENCE;

D O I：

10.1016/j.eurpolymj.2013.10.019

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An efficient way to synthesize an AB-type monomer, bearing a carboxylic acid and an aldehyde moiety, for Passerini step-growth polymerizations is described. This monomer was directly polymerized in a polyaddition approach applying the Passerini three-component reaction. Using various isocyanides for this polymerization resulted in polyesters with different amide side chains. Another structural feature of these polymers is a sulfur containing backbone, which is due to the monomer synthesis via thiol-ene chemistry. Oxidation of these polymers resulted in polysulfones exhibiting tunable thermal properties. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：150 / 157

页数：8

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