Enantioselective Iron Catalysts

被引：23
作者：
Ollevier, Thierry [1 ]
Keipour, Hoda [1 ]
机构：
[1] Univ Laval, Dept Chim, 1045 Ave Med, Quebec City, PQ G1V 0A6, Canada
来源：
IRON CATALYSIS II | 2015年 / 50卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
Alkane hydroxylation; Asymmetric catalysis; Biomimetic oxidation; Catalyst; Homogeneous catalysis; Hydrogenation; Hydrosilylation; Iron; Non-heme; ASYMMETRIC TRANSFER HYDROGENATION; DIELS-ALDER REACTION; TWIN-CORONET PORPHYRINS; MUKAIYAMA-ALDOL REACTIONS; BETA-KETO-ESTERS; SULFIDE OXIDATION; CHIRAL METALLOPORPHYRINS; KINETIC RESOLUTION; METAL-COMPLEXES; BOND FORMATION;
D O I：
10.1007/3418_2015_102
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Synthetic organic transformations catalyzed by iron complexes have attracted considerable attention because of an enviable list of assets: iron is an ubiquitous, inexpensive, and environmentally benign metal. It has been documented that various chiral iron complexes can be used in many reactions such as oxidation, cyclopropanation, hydrogenation, hydrosilylation, and alkane hydroxylation. This chapter summarizes recent developments, mainly from 2004 to 2014, of enantioselective iron catalysts.
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收藏
页码：259 / 309
页数：51
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