Enantioselective Iron Catalysts

被引：23
作者：
Ollevier, Thierry [1 ]
Keipour, Hoda [1 ]
机构：
[1] Univ Laval, Dept Chim, 1045 Ave Med, Quebec City, PQ G1V 0A6, Canada
来源：
IRON CATALYSIS II | 2015年 / 50卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
Alkane hydroxylation; Asymmetric catalysis; Biomimetic oxidation; Catalyst; Homogeneous catalysis; Hydrogenation; Hydrosilylation; Iron; Non-heme; ASYMMETRIC TRANSFER HYDROGENATION; DIELS-ALDER REACTION; TWIN-CORONET PORPHYRINS; MUKAIYAMA-ALDOL REACTIONS; BETA-KETO-ESTERS; SULFIDE OXIDATION; CHIRAL METALLOPORPHYRINS; KINETIC RESOLUTION; METAL-COMPLEXES; BOND FORMATION;
D O I：
10.1007/3418_2015_102
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Synthetic organic transformations catalyzed by iron complexes have attracted considerable attention because of an enviable list of assets: iron is an ubiquitous, inexpensive, and environmentally benign metal. It has been documented that various chiral iron complexes can be used in many reactions such as oxidation, cyclopropanation, hydrogenation, hydrosilylation, and alkane hydroxylation. This chapter summarizes recent developments, mainly from 2004 to 2014, of enantioselective iron catalysts.
引用
收藏
页码：259 / 309
页数：51
相关论文
共 177 条
  • [1] Chemo- and Stereoselective Iron-Catalyzed Hydrosilylation of Ketones
    Addis, Daniele
    Shaikh, Nadim
    Zhou, Shaolin
    Das, Shoubhik
    Junge, Kathrin
    Beller, Matthius
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) : 1687 - 1691
  • [2] Light-Induced Enantioselective Hydrogenation Using Chiral Derivatives of Casey's Iron-Cyclopentadienone Catalyst
    Berkessel, Albrecht
    Reichau, Sebastian
    von der Hoeh, Adrian
    Leconte, Nicolas
    Neudoerfl, Joerg-M.
    [J]. ORGANOMETALLICS, 2011, 30 (14) : 3880 - 3887
  • [3] Isonitrile Iron(II) Complexes with Chiral N2P2 Macrocycles in the Enantioselective Transfer Hydrogenation of Ketones
    Bigler, Raphael
    Mezzetti, Antonio
    [J]. ORGANIC LETTERS, 2014, 16 (24) : 6460 - 6463
  • [4] L-prolinoyl chiral picket iron porphyrins evaluated for the enantioselective epoxidation of alkenes
    Boitrel, B
    Baveux-Chambenoît, V
    [J]. NEW JOURNAL OF CHEMISTRY, 2003, 27 (06) : 942 - 947
  • [5] Boitrel B, 2002, EUR J INORG CHEM, P1666
  • [6] Iron-catalyzed reactions in organic synthesis
    Bolm, C
    Legros, J
    Le Paih, J
    Zani, L
    [J]. CHEMICAL REVIEWS, 2004, 104 (12) : 6217 - 6254
  • [7] Catalytic Enantioselective Hydrophosphonylation of Aldehydes Using the Iron Complex of a Camphor-Based Tridentate Schiff Base [FeCl(SBAIB-d)]2
    Boobalan, Ramalingam
    Chen, Chinpiao
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2013, 355 (17) : 3443 - 3450
  • [8] A new chiral ligand for the Fe-Lewis acid catalysed asymmetric Diels-Alder reaction
    Bruin, ME
    Kundig, EP
    [J]. CHEMICAL COMMUNICATIONS, 1998, (23) : 2635 - 2636
  • [9] Iron-catalyzed oxidation of thioethers by iodosylarenes: Setereoselectivity and reaction mechanism
    Bryliakov, Konstantin P.
    Talsi, Evgenii P.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (28) : 8045 - 8050
  • [10] Evidence for the formation of an iodosylbenzene(salen)iron active intermediate in a (salen)iron (III)-catalyzed asymmetric sulfide oxidation
    Bryliakov, KP
    Talsi, EP
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (39) : 5228 - 5230
12345678910