The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers

被引：1

作者：

Tingare, Yogesh S. ^{[1
]}

Akula, Suri Babu ^{[1
]}

Shen, Ming-Tai ^{[1
]}

Su, Chaochin ^{[2
]}

Ho, Shih-Yu ^{[2
]}

Tsai, Sheng-Han ^{[2
]}

Lin, Ya-Fen ^{[1
]}

Li, Wen-Ren ^{[1
]}

机构：

[1] Natl Cent Univ, Dept Chem, Chungli, Taiwan

[2] Natl Taipei Univ Technol, Inst Organ & Polymer Mat, Taipei, Taiwan

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 25期

关键词：

SOLAR-CELLS; ORGANIC-DYES; EFFICIENCY; COMPLEXES; CONVERSION; LIGHT; ELECTROLYTE; ELECTRICITY; SUNLIGHT; LIGANDS;

D O I：

10.1039/c8dt01131a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (eta) of 7.27% than that of the cis configured complex (eta = 2.04%).

引用

页码：8356 / 8363

页数：8

共 49 条

[1] Synthesis of multinuclear pyridylimine based palladium(II) complexes with a functionalized star polystyrene core and evaluation of their catalytic activity towards ethylene oligomerization
Abraham, Sinoj
Ha, Chang-Sik
Kim, Il
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (16) : 1386 - 1392
[2] [Anonymous], 2006, ANGEW CHEM, DOI DOI 10.1002/ANGE.200601463
[3] Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst
Balula, Salete S.
Bruno, Sofia M.
Gomes, Ana C.
Valente, Anabela A.
Pillinger, Martyn
Goncalves, Isabel S.
Macquarrie, Duncan J.
Clark, James H.
[J]. INORGANICA CHIMICA ACTA, 2012, 387 : 234 - 239
[4] Cyclometalated ruthenium chromophores for the dye-sensitized solar cell
Bomben, Paolo G.
Robson, Kiyoshi C. D.
Koivisto, Bryan D.
Berlinguette, Curtis P.
[J]. COORDINATION CHEMISTRY REVIEWS, 2012, 256 (15-16) : 1438 - 1450
[5] Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells
Boschloo, Gerrit
Hagfeldt, Anders
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) : 1819 - 1826
[6] Remarkable effects of primary amide substitution in the sensitizer: an efficient route to enhance the photocurrent density of the solar cell
Chang, Wei-Chun
Su, Chaochin
Ho, Shih-Yu
Prabakaran, Kumaresan
Tingare, Yogesh S.
Li, Chung-Yen
Li, Ting-Yu
Tsai, Sheng-Han
Li, Wen-Ren
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (31) : 8716 - 8720
[7] Highly Efficient N-Heterocyclic Carbene/Pyridine-Based Ruthenium Sensitizers: Complexes for Dye-Sensitized Solar Cells
Chang, Wei-Chun
Chen, Huei-Siou
Li, Ting-Yu
Hsu, Nai-Mu
Tingare, Yogesh S.
Li, Chung-Yen
Liu, Yi-Cheng
Su, Chaochin
Li, Wen-Ren
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (44) : 8161 - 8164
[8] Multifunctionalized ruthenium-based supersensitizers for highly efficient dye-sensitized solar cells
Chen, Chia-Yuan
Chen, Jian-Ging
Wu, Shi-Jhang
Li, Jheng-Ying
Wu, Chun-Guey
Ho, Kuo-Chuan
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (38) : 7342 - 7345
[9] Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells
Chen, Chia-Yuan
Wang, Mingkui
Li, Jheng-Ying
Pootrakulchote, Nuttapol
Alibabaei, Leila
Ngoc-le, Cevey-ha
Decoppet, Jean-David
Tsai, Jia-Hung
Graetzel, Carole
Wu, Chun-Guey
Zakeeruddin, Shaik M.
Graetzel, Michael
[J]. ACS NANO, 2009, 3 (10) : 3103 - 3109
[10] Ruthenium and Osmium Complexes That Bear Functional Azolate Chelates for Dye-Sensitized Solar Cells
Chi, Yun
Wu, Kuan-Lin
Wei, Tzu-Chien
[J]. Chemistry-An Asian Journal, 2015, 10 (05) : 1098 - 1115

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