Synthesis and Characterization of Iron Derivatives Having a Pyridine-Linked Bis(anilide) Pincer Ligand

被引：14

作者：

Weintrob, Edward C. ^{[1
]}

Tofan, Daniel ^{[1
]}

Bercaw, John E. ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 08期

关键词：

CROSS-COUPLING REACTIONS; CATALYTIC-HYDROGENATION; ORGANIC-SYNTHESIS; COMPLEXES; REACTIVITY; EFFICIENT; METAL; DEPROTONATION; PURIFICATION; OXIDATION;

D O I：

10.1021/ic900083s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A pyridine-linked bis(aniline) pincer ligand, [2]H-2 ([2]H-2 = (2,6-NC5H3(2-(2,4,6-Me3C6H2)-NHC6H4)(2)), has been synthesized in two steps. Deprotonation with Me3SiCH2Li followed by metalation with FeCl2 yielded a LiCl adduct of [2]Fe. The complex is freed of LiCl with excess TIPF6 or by crystallization from toluene/petroleum ether, giving [2]Fe(THF). [2]Fe(THF) reacts with I-2 and O-2 to generate [2]FeI and ([2]Fe)(2)O, respectively. The complexes have been characterized by H-1 NMR spectroscopy, elemental analysis, X-ray crystallography, and UV-vis spectroscopy. [2]Fe(THF) has been examined using cyclic voltammetry.

引用

页码：3808 / 3813

页数：6

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