Carbon nanotubes based high temperature vulcanized silicone rubber nanocomposite with excellent elasticity and electrical properties

被引:88
作者
Shang, Songmin [1 ]
Gan, Lu [1 ]
Yuen, Chun Wah Marcus [1 ]
Jiang, Shou-xiang [1 ]
Luo, Nicy Mei [1 ]
机构
[1] Hong Kong Polytech Univ, Inst Text & Clothing, Hong Kong, Hong Kong, Peoples R China
关键词
Polymer-matrix composites (PMCs); Electrical properties; Elasticity; High temperature vulcanized silicone rubber; MECHANICAL-PROPERTIES; SENSING BEHAVIORS; COMPOSITES; STRAIN; PRESSURE; SENSOR; WATER; CRYSTALLIZATION; RESISTANCE; DISPERSION;
D O I
10.1016/j.compositesa.2014.07.014
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the present study, we have fabricated a series of high temperature vulcanized silicone rubber (HTVSR)/carbon nanotubes (CNTs) nanocomposites with different CNT contents. The CNTs were pretreated by the chitosan salt before being incorporated into the HTVSR. The nanocomposites were then characterized in terms of morphological, thermal, mechanical and electrical properties. It was found that the chitosan salt pretreated CNTs dispersed uniformly within the HTVSR matrix, improving the thermal and mechanical properties of the HTVSR. The nanocomposites could remain conductive without losing inherent properties after 100 times of repeated stretching/release cycles by 100%, 200%, and even 300%. Moreover, the nanocomposites had good response to the compressed pressures. The results obtained from this study indicate that the fabricated nanocomposites are potential to be used in many electrical fields such as the conductive elastomer or the pressure sensor. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:135 / 141
页数:7
相关论文
共 40 条
[1]   A review and analysis of electrical percolation in carbon nanotube polymer composites [J].
Bauhofer, Wolfgang ;
Kovacs, Josef Z. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (10) :1486-1498
[2]   Multiwall carbon nanotube elastomeric composites: A review [J].
Bokobza, Liliane .
POLYMER, 2007, 48 (17) :4907-4920
[3]   Single-walled carbon nanotube dispersions in poly(ethylene oxide) [J].
Chatterjee, T ;
Yurekli, K ;
Hadjiev, VG ;
Krishnamoorti, R .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (11) :1832-1838
[4]   A Highly Elastic, Capacitive Strain Gauge Based on Percolating Nanotube Networks [J].
Cohen, Daniel J. ;
Mitra, Debkishore ;
Peterson, Kevin ;
Maharbiz, Michel M. .
NANO LETTERS, 2012, 12 (04) :1821-1825
[5]   Small but strong: A review of the mechanical properties of carbon nanotube-polymer composites [J].
Coleman, Jonathan N. ;
Khan, Umar ;
Blau, Werner J. ;
Gun'ko, Yurii K. .
CARBON, 2006, 44 (09) :1624-1652
[6]   Supersensitive linear piezoresistive property in carbon nanotubes/silicone rubber nanocomposites [J].
Dang, Zhi-Min ;
Jiang, Mei-Juan ;
Xie, Dan ;
Yao, Sheng-Hong ;
Zhang, Li-Qun ;
Bai, Jinbo .
JOURNAL OF APPLIED PHYSICS, 2008, 104 (02)
[7]   High weight fraction surfactant solubilization of single-wall carbon nanotubes in water [J].
Islam, MF ;
Rojas, E ;
Bergey, DM ;
Johnson, AT ;
Yodh, AG .
NANO LETTERS, 2003, 3 (02) :269-273
[8]   Effect of aspect ratio of multiwall carbon nanotubes on resistance-pressure sensitivity of rubber nanocomposites [J].
Jiang, Mei-Juan ;
Dang, Zhi-Min ;
Xu, Hai-Ping ;
Yao, Sheng-Hong ;
Bai, Jinbo .
APPLIED PHYSICS LETTERS, 2007, 91 (07)
[9]   Giant dielectric constant and resistance-pressure sensitivity in carbon nanotubes/rubber nanocomposites with low percolation threshold [J].
Jiang, Mei-Juan ;
Dang, Zhi-Min ;
Xu, Hai-Ping .
APPLIED PHYSICS LETTERS, 2007, 90 (04)
[10]   Enhanced electrical conductivity in chemically modified carbon nanotube/methylvinyl silicone rubber nanocomposite [J].
Jiang, Mei-Juan ;
Dang, Zhi-Min ;
Xu, Hal-Ping .
EUROPEAN POLYMER JOURNAL, 2007, 43 (12) :4924-4930