Effect of (Ba+Sr)/Ti ratio on dielectric and tunable properties of Ba0.6Sr0.4TiO3 thin film prepared by sol-gel method

被引:7
作者
Zhu Wei-cheng [1 ]
Peng Dong-wen [1 ]
Cheng Jin-rong [1 ]
Meng Zhong-yan [1 ]
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200072, Peoples R China
来源
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2006年 / 16卷 / s261-s265期
基金
中国国家自然科学基金;
关键词
Ba0.6Sr0.4TiO3 thin film; (Ba plus Sr)/Ti ratio; sol-gel method; dielectric properties;
D O I
10.1016/S1003-6326(06)60187-8
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Ba0.6Sr0.4TiO3 (BST) thin films were fabricated on Pt coated Si (100) substrates by sol-gel techniques with molar ratio of (Ba+Sr) to Ti changing from 0.76 to 1.33. The effect of (Ba+Sr)/Ti ratio deviating from the stoichiometry on microstructure, grain growth, dielectric and tunable properties of BST thin films were investigated. TiO2 and (Ba,Sr)(2)TiO4 were found as a second phase at the ratios of 0.76 and 1.33, respectively. The variation of the ratio reveals more significant effect on the grain size in B-site rich samples than that in A-site rich samples. The dissipation factor decreases rapidly from 0.1 to 0.01 at 1 MHz with decreasing (Ba+Sr)/Ti ratio. The tunability increases with decreasing ratio from 1.33 to 1.05, and then decreases with decreasing ratio from 1.05 to 0.76. The film with (Ba+Sr)/Ti ratio of 1.05 has a maximum tunability of 32% and a dissipation factor of 0.03 at 1 MHz.
引用
收藏
页码:S261 / S265
页数:5
相关论文
共 20 条
[11]  
Lee JK, 2001, J AM CERAM SOC, V84, P2001
[12]   Sol-gel derived grain oriented barium strontium titanate thin films for phase shifter applications [J].
Majumder, SB ;
Jain, M ;
Martinez, A ;
Katiyar, RS ;
Van Keuls, FW ;
Miranda, FA .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (02) :896-903
[13]   Investigation of Ba2-xSrxTiO4:: Structural aspects and dielectric properties [J].
Shanker, V ;
Ahmad, T ;
Ganguli, AK .
BULLETIN OF MATERIALS SCIENCE, 2004, 27 (05) :421-427
[14]   Ferroelectricity in thin films:: The dielectric response of fiber-textured (BaxSr1-x)Ti1+yO3+z thin films grown by chemical vapor deposition [J].
Streiffer, SK ;
Basceri, C ;
Parker, CB ;
Lash, SE ;
Kingon, AI .
JOURNAL OF APPLIED PHYSICS, 1999, 86 (08) :4565-4575
[15]   Ruddlesden-Popper planar faults and nanotwins in heteroepitaxial nonstoichiometric barium titanate thin films [J].
Suzuki, T ;
Nishi, Y ;
Fujimoto, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (12) :3185-3195
[16]   First-principles structural stability study of nonstoichiometry-related planar defects in SrTiO3 and BaTiO3 [J].
Suzuki, T ;
Fujimoto, M .
JOURNAL OF APPLIED PHYSICS, 2001, 89 (10) :5622-5629
[17]   Effect of nonstoichiometry on the microstructure and dielectric properties of strontium titanate ceramics [J].
Tkach, A ;
Vilarinho, PM ;
Senos, AMR ;
Kholkin, AL .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (12) :2769-2772
[18]   Micromachined systems for RF and microwave antenna applications [J].
Vinoy, KJ ;
Sharma, PK ;
Jose, KA ;
Varadan, VK ;
Varadan, VV .
SMART STRUCTURES AND MATERIALS 2001: SMART ELECTRONICS AND MEMS, 2001, 4334 :156-163
[19]  
Wu L, 2000, J AM CERAM SOC, V83, P1713
[20]   (BA+SR)/TI RATIO DEPENDENCE OF THE DIELECTRIC-PROPERTIES FOR (BA.05SR0.5)TIO3 THIN-FILMS PREPARED BY ION-BEAM SPUTTERING [J].
YAMAMICHI, S ;
YABUTA, H ;
SAKUMA, T ;
MIYASAKA, Y .
APPLIED PHYSICS LETTERS, 1994, 64 (13) :1644-1646