Effect of (Ba+Sr)/Ti ratio on dielectric and tunable properties of Ba0.6Sr0.4TiO3 thin film prepared by sol-gel method

被引:7
作者
Zhu Wei-cheng [1 ]
Peng Dong-wen [1 ]
Cheng Jin-rong [1 ]
Meng Zhong-yan [1 ]
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200072, Peoples R China
来源
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2006年 / 16卷 / s261-s265期
基金
中国国家自然科学基金;
关键词
Ba0.6Sr0.4TiO3 thin film; (Ba plus Sr)/Ti ratio; sol-gel method; dielectric properties;
D O I
10.1016/S1003-6326(06)60187-8
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Ba0.6Sr0.4TiO3 (BST) thin films were fabricated on Pt coated Si (100) substrates by sol-gel techniques with molar ratio of (Ba+Sr) to Ti changing from 0.76 to 1.33. The effect of (Ba+Sr)/Ti ratio deviating from the stoichiometry on microstructure, grain growth, dielectric and tunable properties of BST thin films were investigated. TiO2 and (Ba,Sr)(2)TiO4 were found as a second phase at the ratios of 0.76 and 1.33, respectively. The variation of the ratio reveals more significant effect on the grain size in B-site rich samples than that in A-site rich samples. The dissipation factor decreases rapidly from 0.1 to 0.01 at 1 MHz with decreasing (Ba+Sr)/Ti ratio. The tunability increases with decreasing ratio from 1.33 to 1.05, and then decreases with decreasing ratio from 1.05 to 0.76. The film with (Ba+Sr)/Ti ratio of 1.05 has a maximum tunability of 32% and a dissipation factor of 0.03 at 1 MHz.
引用
收藏
页码:S261 / S265
页数:5
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