Reduction of pesticide residues from tomatoes by low intensity electrical current and ultrasound applications

被引:65
作者
Cengiz, Mehmet Fatih [1 ]
Baslar, Mehmet [2 ]
Basancelebi, Onur [3 ]
Kilicli, Mahmut [2 ]
机构
[1] Akdeniz Univ, Food Safety & Agr Res Ctr, TR-07058 Antalya, Turkey
[2] Yildiz Tech Univ, Chem & Met Engn Fac, Food Engn Dept, TR-34210 Istanbul, Turkey
[3] Akdeniz Univ, Engn Fac, Food Engn Dept, TR-07058 Antalya, Turkey
基金
美国国家科学基金会;
关键词
Low intensity electrical current; Pesticide residue; Tomato; Ultrasound; DOPED DIAMOND ELECTRODES; PHOTO-FENTON; DEGRADATION; OXIDATION; WATER; REMOVAL; PERSPECTIVES; TECHNOLOGY; PARAMETERS; KINETICS;
D O I
10.1016/j.foodchem.2017.08.031
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this study, effects of low intensity electrical current (EC) and ultrasound (US) treatments on the reduction of some important pesticides (captan, thiamethoxam and metalaxyl) residues in tomato samples were investigated. Three different currents (200, 800 and 1400 mA) of EC were applied at various time intervals (2, 4, 6, 8 and 10 min). Two kinds of US treatments including ultrasonic bath (UB) at 40 kHz and ultrasonic probe (UP) at 24 kHz were tested for the determination of US effectiveness. In addition, synergistic effects of US on EC treatments were evaluated. The most effective conditions for reduction of captan, thiamethoxam and metalaxyl residues were 1400 mA + 40 kHz, 800 mA + 24 kHz and 1400 mA + 24 kHz, respectively. The residues of captan, thiamethoxam and metalaxyl were reduced in the order of 94.24%, 69.80% and 95.06% by using these combinations. EC and US strategies can be considered as effective treatments in industrial scale in order to remove the pesticide residues from vegetables.
引用
收藏
页码:60 / 66
页数:7
相关论文
共 40 条
[21]   Synergistic sonoelectrochemical removal of substituted phenols: Implications of ultrasonic parameters and physicochemical properties [J].
Kim, Kyungho ;
Cho, Eunju ;
Thokchom, Binota ;
Cui, Mingcan ;
Jang, Min ;
Khim, Jeehyeong .
ULTRASONICS SONOCHEMISTRY, 2015, 24 :172-177
[22]   Removal of chloropyrifos ethyl, tetradifon and chlorothalonil pesticide residues from citrus by using ozone [J].
Kusvuran, Erdal ;
Yildirim, Deniz ;
Mavruk, Funda ;
Ceyhan, Mehmet .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 241 :287-300
[23]  
Leite RHD, 2002, CHEM ENG SCI, V57, P767
[24]   Evaluation of antioxidant properties of pomegranate peel extract in comparison with pomegranate pulp extract [J].
Li, YF ;
Guo, CJ ;
Yang, JJ ;
Wei, JY ;
Xu, J ;
Cheng, S .
FOOD CHEMISTRY, 2006, 96 (02) :254-260
[25]   Effects of home preparation on organophosphorus pesticide residues in raw cucumber [J].
Liang, Y. ;
Wang, W. ;
Shen, Y. ;
Liu, Y. ;
Liu, X. J. .
FOOD CHEMISTRY, 2012, 133 (03) :636-640
[26]   The development, validation and application of a GC-dual detector (NPD-ECD) multi-pesticide residue method for monitoring bee poisoning incidents [J].
Lozowicka, Bozena .
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2013, 97 :210-222
[27]   Degradation of sodium dodecylbenzene sulfonate in water by ultrasonic irradiation [J].
Manousaki, E ;
Psillakis, E ;
Kalogerakis, N ;
Mantzavinos, D .
WATER RESEARCH, 2004, 38 (17) :3751-3759
[28]   Fenton and Fenton-like oxidation of pesticide acetamiprid in water samples: Kinetic study of the degradation and optimization using response surface methodology [J].
Mitsika, Elena E. ;
Christophoridis, Christophoros ;
Fytianos, Konstantinos .
CHEMOSPHERE, 2013, 93 (09) :1818-1825
[29]   Pesticides and human chronic diseases: Evidences, mechanisms, and perspectives [J].
Mostafalou, Sara ;
Abdollahi, Mohammad .
TOXICOLOGY AND APPLIED PHARMACOLOGY, 2013, 268 (02) :157-177
[30]   Thiamethoxam is a neonicotinoid precursor converted to clothianidin in insects and plants [J].
Nauen, R ;
Ebbinghaus-Kintscher, U ;
Salgado, VL ;
Kaussmann, M .
PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 2003, 76 (02) :55-69