Molecular design of n-type organic semiconductors for high-performance thin film transistors

被引:45
|
作者
Shan, Bowen [1 ]
Miao, Qian [1 ,2 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[2] Univ Grants Comm, Inst Mol Funct Mat, Area Excellence Scheme, Hong Kong, Hong Kong, Peoples R China
关键词
Organic semiconductors; Organic thin film transistors; Molecular design; Conjugated molecules; FIELD-EFFECT TRANSISTORS; HIGH-ELECTRON-MOBILITY; SELF-ASSEMBLED MONOLAYERS; CM(2) V-1 S(-1); SINGLE-CRYSTAL TRANSISTORS; ORBITAL ENERGY-LEVELS; CHARGE-TRANSPORT; NAPHTHALENE-DIIMIDE; TRIFLUOROMETHYLPHENYL GROUPS; POLYMER SEMICONDUCTORS;
D O I
10.1016/j.tetlet.2017.04.023
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This digest aims to provide organic chemists with an overview of recent progress on n-type organic semiconductors for application in organic thin film transistors (OTFTs) with an emphasis on molecular design. Herein, we survey n-type organic semiconductors with field effect mobility of 1 cm(2)/Vs or higher in OTFTs after a brief introduction to the structure and operation of OTFTs and discussion of two key factors (frontier molecular orbitals and molecular packing) of organic semiconductors. On the basis of this survey, we finally reach conclusions on the current status of n-type organic semiconductors for OTFTs and provide an outlook for molecular design. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1903 / 1911
页数:9
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