Synthesis and crystal structure of a trinuclear Zn(II) complex

被引：0

作者：

Ling-Yan, Kong ^{[1
]}

Yong-Qing, Huang ^{[1
]}

Xi-Hong, Lu ^{[1
]}

Guang-Xiang, Liu ^{[1
]}

Wei-Yin, Sun ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 22卷 / 08期

关键词：

tripodal ligand; crystal structure; Zn(II) complex;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A trinuclear Zn(II) complex [Zn-3(L)(2)(Cl)(2)(OSO3)(2)(H2O)(.)2H(2)O (1) (L=N'-(2-aminoethyl)-N-1-(2-imidazolethyl)-ethane-1,2-diamine) was synthesized by reaction of ligand L with ZnSO4-7H(2)O at pH=9 in air. The complex has been characterized by elemental analysis, FTIR and X-ray single crystal diffraction. It reveals that the crystal of complex 1 belongs to monoclinic C2/c space group, a=3.5169(7) run, b=0.67657(14) nm, c=1.5022(3) nm, beta=110.955(4)degrees, V=3.337 9(12) nm(3), Z=4. In complex 1, two ligands L bridge three Zn(II) centers to form trinuclear structure which was further connected by hydrogen bonding to form two-dimensional structure.

引用

页码：1484 / 1486

页数：3

共 11 条

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