High-Rate Oxygen Evolution Reaction on Al-Doped LiNiO2

被引：87
|
作者：
Gupta, Asha [1 ]
Chemelewski, William D. [1 ]
Mullins, C. Buddie [1 ,2 ,3 ]
Goodenough, John B. [1 ]
机构：
[1] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
[2] Univ Texas Austin, McKetta Dept Chem Engn, Austin, TX 78712 USA
[3] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA
来源：
ADVANCED MATERIALS | 2015年 / 27卷 / 39期
关键词：
Al-doped LiNiO2; electrocatalysis; oxygen evolution reaction; solution combustion synthesis; X-ray photoelectron spectroscopy (XPS); ELECTROCHEMICAL PROPERTIES; WATER OXIDATION; ALKALINE MEDIA; OXIDE; REDUCTION; BATTERIES; CATALYSTS; NANOSTRUCTURES; EFFICIENT; ALUMINUM;
D O I：
10.1002/adma.201502256
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
LiNi0.8Al0.2O2 with a higher Ni3+/Li+ ordering, synthesized by the solution-combustion method, gives oxygen-evolution-reaction (OER) activity in alkaline solution that is comparable to that of IrO2. This confirms that the octahedral-site Ni-IV/Ni-III couple in an oxide is an active redox center for the OER with redox energy pinned at the top of the O-2p bands.
引用
收藏
页码：6063 / 6067
页数：5
相关论文
共 50 条
  • [1] The Effect of Cation Mixing in LiNiO2 toward the Oxygen Evolution Reaction
    Ren, Yadan
    Yamaguchi, Ryusei
    Uchiyama, Tomoki
    Orikasa, Yuki
    Watanabe, Toshiki
    Yamamoto, Kentaro
    Matsunaga, Toshiyuki
    Nishiki, Yoshinori
    Mitsushima, Shigenori
    Uchimoto, Yoshiharu
    CHEMELECTROCHEM, 2021, 8 (01) : 70 - 76
  • [2] Layered Fe-Substituted LiNiO2 Electrocatalysts for High-Efficiency Oxygen Evolution Reaction
    Zhu, Kaiyue
    Wu, Tao
    Zhu, Yue
    Li, Xuning
    Li, Mingrun
    Lu, Ruifeng
    Wang, Junhu
    Zhu, Xuefeng
    Yang, Weishen
    ACS ENERGY LETTERS, 2017, 2 (07): : 1654 - 1660
  • [3] Electrochemical properties of LiNiO2 and LiNiO2 substituted with Ga, Al and/or Ti
    Park, Hye Ryoung
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2010, 16 (05) : 698 - 702
  • [4] Fabrication of cobalt doped titania for enhanced oxygen evolution reaction
    Abbas, Mohsin
    ul Haq, Tanveer
    Arshad, Salman Noshear
    Zaheer, Muhammad
    MOLECULAR CATALYSIS, 2020, 488
  • [5] Structural evolution and reaction mechanism of lithium nickelate (LiNiO2) during the carbonation reaction
    Gonzalez-Varela, Daniela
    Alcantar-vazquez, Brenda
    Pfeiffer, Heriberto
    JOURNAL OF MATERIOMICS, 2018, 4 (01) : 56 - 61
  • [6] Kinetic Stability of Bulk LiNiO2 and Surface Degradation by Oxygen Evolution in LiNiO2-Based Cathode Materials
    Kong, Fantai
    Liang, Chaoping
    Wang, Luhua
    Zheng, Yongping
    Perananthan, Sahila
    Longo, Roberto C.
    Ferraris, John P.
    Kim, Moon
    Cho, Kyeongjae
    ADVANCED ENERGY MATERIALS, 2019, 9 (02)
  • [7] Co ion-intercalation amorphous and ultrathin microstructure for high-rate oxygen evolution
    Zhao, Changtai
    Yu, Chang
    Huang, Huawei
    Han, Xiaotong
    Liu, Zhibin
    Qiu, Jieshan
    ENERGY STORAGE MATERIALS, 2018, 10 : 291 - 296
  • [8] Highly Active and Stable Al-Doped NiFe Self-Supported Oxygen Evolution Reaction Electrode for Alkaline Water Electrolysis
    Lee, Byung-Jo
    Jung, Sang-Mun
    Yu, Gwonho
    Kim, Hyun-Yup
    Kwon, Jaesub
    Kim, Kyu-Su
    Kwak, Jaeik
    Lee, Wooseok
    Mok, Dong Hyeon
    Back, Seoin
    Kim, Yong-Tae
    ACS CATALYSIS, 2025, 15 (02): : 1123 - 1134
  • [9] Coordination compound-derived Al-doped Fe3O4/C as an efficient electrocatalyst for oxygen evolution reaction
    Cui, Lei Lei
    Liu, Xing
    Gong, Yun
    JOURNAL OF SOLID STATE CHEMISTRY, 2022, 310
  • [10] First principles investigation of the structure and stability of LiNiO2 doped with Co and Mn
    Kim, Yongseon
    JOURNAL OF MATERIALS SCIENCE, 2012, 47 (21) : 7558 - 7563
12345