Low Glass Transition Temperature Polymer Electrolyte Prepared From Ionic Liquid Grafted Polyethylene Oxide

被引：77
|
作者：
Hu, Heyi [1 ]
Yuan, Wen [1 ]
Lu, Lanshuo [2 ]
Zhao, Hui [1 ]
Jia, Zhe [1 ]
Baker, Gregory L. [1 ]
机构：
[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci CCEMS, Suzhou 215123, Jiangsu, Peoples R China
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2014年 / 52卷 / 15期
基金：
美国国家科学基金会;
关键词：
anionic ring-opening polymerization; anionic polymerization; cationic ring-opening polymerization; conducting polymers; conductivity; glass transition temperature; glass transition; poly (ionic liquids); viscosity; GAS SEPARATION MEMBRANES; POLY(IONIC LIQUID)S; MOLECULAR-WEIGHT; CONDUCTIVITY; ABSORPTION; COPOLYMERS; BRUSH; FILMS;
D O I：
10.1002/pola.27217
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this contribution, we report a new type of poly (ionic liquids) prepared by imidazolium ionic liquids directly grafting onto polyethylene oxide backbone. Different molecular weights of poly (ionic liquids) are obtained with a low glass transition temperature up to -14 degrees C. The materials as polymer electrolyte achieve a high conductivity around 10 (-5) S cm(-1) at 30 degrees C and close to 10(-3) S cm(-1) at 90 degrees C. High viscosity up to 4000 Pa s at room temperature would minimize the electrolytes leaking in electrochemical devices. (C) 2014 Wiley Periodicals, Inc.
引用
收藏
页码：2104 / 2110
页数：7
相关论文
共 50 条
  • [31] New all solid-state polymer electrolyte based on epoxy resin and ionic liquid for high temperature applications
    Oliveira da Silva, Luis Carlos
    Soares, Bluma Guenther
    JOURNAL OF APPLIED POLYMER SCIENCE, 2018, 135 (09)
  • [32] Glass Transition Temperature of Polymer Nanocomposites: Prediction from the Continuous-Multilayer Model
    Ahn, Sung Il
    Ohk, Chang Woo
    Kim, Jae Hyun
    Zin, Wang-Cheol
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2009, 47 (22) : 2281 - 2287
  • [33] Electrochemical performance of gel polymer electrolyte with ionic liquid and PUA/PMMA prepared by ultraviolet curing technology for lithium-ion battery
    Li, Libo
    Wang, Furi
    Li, Jiesi
    Yang, Xueying
    You, Jun
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (17) : 12087 - 12093
  • [34] High Performance Polymer/Ionic Liquid Thermoplastic Solid Electrolyte Prepared by Solvent Free Processing for Solid State Lithium Metal Batteries
    Gonzalez, Francisco
    Tiemblo, Pilar
    Garcia, Nuria
    Garcia-Calvo, Oihane
    Fedeli, Elisabetta
    Kvasha, Andriy
    Urdampilleta, Idoia
    MEMBRANES, 2018, 8 (03)
  • [35] Electric Double-Layer Capacitance of Inverse Opal Carbon Prepared Through Carbonization of Poly(Furfuryl Alcohol) in Contact With Polymer Gel Electrolyte Containing Ionic Liquid
    Isshiki, Yusuke
    Nakamura, Megumi
    Tabata, Seiichiro
    Dokko, Kaoru
    Watanabe, Masayoshi
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (08) : 1254 - 1260
  • [36] The Improvement of Electro-Optical Properties of Polymer-Dispersed Liquid Crystals using Copolymer Macroinitiator with Different Glass Transition Temperature
    Du, Xin
    Yan, Bin
    Yao, Jiali
    Chen, Shu
    Li, Minke
    Wang, Yinghan
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (23) : 5557 - 5561
  • [37] One-dimensional sepiolite confined ionic liquids structure to improve the electrochemical performance of polyethylene-oxide based composite polymer electrolyte
    Zhang, Yanhua
    Mei, Yuhang
    Gao, Xinglong
    Xiao, Yumei
    Tang, Zijun
    Xiang, Xing
    Deng, Jiadong
    JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 970
  • [38] Diamond nanothread reinforced polymer composites: Ultra-high glass transition temperature and low density
    Ji, W. M.
    Zhang, L. W.
    COMPOSITES SCIENCE AND TECHNOLOGY, 2019, 183
  • [39] Structure, ion transport, and relaxation dynamics of polyethylene oxide/poly (vinylidene fluoride co-hexafluoropropylene)-lithium bis(trifluoromethane sulfonyl) imide blend polymer electrolyte embedded with ionic liquid
    Das, S.
    Ghosh, A.
    JOURNAL OF APPLIED PHYSICS, 2016, 119 (09)
  • [40] A polyethylene oxide based electrolyte enabled by the synergistic effect of active LiGaO2 filler and ionic liquid for superior lithium metal batteries
    Luo, Xiongwei
    Xu, Xijun
    Li, Fangkun
    Ji, Shaomin
    Fan, Weizhen
    Zhao, Jingwei
    Liu, Jun
    Huo, Yanping
    JOURNAL OF POWER SOURCES, 2024, 618
12345