Low Glass Transition Temperature Polymer Electrolyte Prepared From Ionic Liquid Grafted Polyethylene Oxide

被引：77

作者：

Hu, Heyi ^{[1
]}

Yuan, Wen ^{[1
]}

Lu, Lanshuo ^{[2
]}

Zhao, Hui ^{[1
]}

Jia, Zhe ^{[1
]}

Baker, Gregory L. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci CCEMS, Suzhou 215123, Jiangsu, Peoples R China

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2014年 / 52卷 / 15期

基金：

美国国家科学基金会;

关键词：

anionic ring-opening polymerization; anionic polymerization; cationic ring-opening polymerization; conducting polymers; conductivity; glass transition temperature; glass transition; poly (ionic liquids); viscosity; GAS SEPARATION MEMBRANES; POLY(IONIC LIQUID)S; MOLECULAR-WEIGHT; CONDUCTIVITY; ABSORPTION; COPOLYMERS; BRUSH; FILMS;

D O I：

10.1002/pola.27217

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this contribution, we report a new type of poly (ionic liquids) prepared by imidazolium ionic liquids directly grafting onto polyethylene oxide backbone. Different molecular weights of poly (ionic liquids) are obtained with a low glass transition temperature up to -14 degrees C. The materials as polymer electrolyte achieve a high conductivity around 10 (-5) S cm(-1) at 30 degrees C and close to 10(-3) S cm(-1) at 90 degrees C. High viscosity up to 4000 Pa s at room temperature would minimize the electrolytes leaking in electrochemical devices. (C) 2014 Wiley Periodicals, Inc.

引用

页码：2104 / 2110

页数：7

共 50 条

[1] Low glass transition temperature poly(ionic liquid) prepared from a new quaternary ammonium cationic monomer
He, Hongkun
Chung, Heesung
Roth, Elliot
Luebke, David
Hopkinson, David
Nulwala, Hunaid
Matyjaszewski, Krzysztof
POLYMERS FOR ADVANCED TECHNOLOGIES, 2015, 26 (07) : 823 - 828
[2] Ionic liquid-based random copolymers: a new type of polymer electrolyte with low glass transition temperature
Hu, Heyi
Yuan, Wen
Jia, Zhe
Baker, Gregory L.
RSC ADVANCES, 2015, 5 (05): : 3135 - 3140
[3] Gelled Ionic Liquid/PMMA Polymer Electrolyte Prepared by Radical Polymerization
Li, Li-bo
Yang, Shuo
Li, Jie-si
Guo, Shao-wen
CHINESE JOURNAL OF CHEMICAL PHYSICS, 2014, 27 (04) : 485 - 490
[4] Influence of temperature on ionic liquid-based gel polymer electrolyte prepared by electrospun fibrous membrane
Kim, Jae-Kwang
Ahn, Jou-Hyeon
Jacobsson, Per
ELECTROCHIMICA ACTA, 2014, 116 : 321 - 325
[5] A Dual Ionic Liquid-Based Low-Temperature Electrolyte System
Xu, Yifei
Lin, Wendy J.
Gliege, Marisa
Gunckel, Ryan
Zhao, Zuofeng
Yu, Hongyu
Dai, Lenore L.
JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 122 (50) : 12077 - 12086
[6] Poly(ionic liquid)-polyethylene oxide semi-interpenetrating polymer network solid electrolyte for safe lithium metal batteries
Li, Yuhan
Sun, Zongjie
Shi, Lei
Lu, Shiyao
Sun, Zehui
Shi, Yuchuan
Wu, Hu
Zhang, Yanfeng
Ding, Shujiang
CHEMICAL ENGINEERING JOURNAL, 2019, 375
[7] A polybenzimidazole/ionic-liquid-graphite-oxide composite membrane for high temperature polymer electrolyte membrane fuel cells
Xu, Chenxi
Liu, Xiaoteng
Cheng, Jigui
Scott, Keith
JOURNAL OF POWER SOURCES, 2015, 274 : 922 - 927
[8] Thermal Properties of Particle Brush Materials: Effect of Polymer Graft Architecture on the Glass Transition Temperature in Polymer-Grafted Colloidal Systems
Dang, Alei
Hui, Chin Ming
Ferebee, Rachel
Kubiak, Joshua
Li, Tiehu
Matyjaszewski, Krzysztof
Bockstaller, Michael R.
MACROMOLECULAR SYMPOSIA, 2013, 331 (01) : 9 - 16
[9] Ionic transport and glass transition temperature of polyether-salt complexes: dependence on molecular mass of polymer
Chan, C. H.
Sim, L. H.
Kammer, H. W.
Tan, W.
Nasir, N. H. Abdul
MATERIALS RESEARCH INNOVATIONS, 2011, 15 : 14 - 17
[10] The polymer composite electrolyte with polyethylene oxide-grafted graphene oxide as fillers toward stable highcurrent density lithium metal anodes
Zhao, Xiaoming
Wu, Zhouhao
Zhang, Zenghui
Wang, Ning
Tao, Cheng-An
Wang, Jianfang
Gong, Hang
MATERIALS RESEARCH EXPRESS, 2021, 8 (10)

← 1 2 3 4 5 →