Developments in the coordination chemistry of stibine ligands

被引：93

作者：

Levason, William ^{[1
]}

Reid, Gillian ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 19-20期

关键词：

antimony ligands; stibines; metal complexes; distibines; bismuthines;

D O I：

10.1016/j.ccr.2006.03.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Developments in the chemistry of stibine and bismuthine ligands in the period 1991-2005 are reviewed. The article describes in turn, new ligand syntheses, ligand properties including bonding and steric effects, trans influence and trans effects. The recent identification of monostibines as bridging ligands is also discussed. This is followed by sequential review of the metal complexes of tertiary monostibines, distibines, polydentates and bismuthines; compounds containing direct Sb-Sb or Bi-Bi bonds are excluded. (c) 2006 Elsevier B.V. All rights reserved.

引用

收藏

页码：2565 / 2594

页数：30

相关论文

共 258 条

[1] Phosphine-stabilized copper-antimony clusters:: Syntheses, structures, and theoretical investigations of [Cu12(SbSiMe3)6(PiPr3)6], [Cu40Sb12(PMe3)20], and [Cu45Sb16(PEt2Me)16] [J].

Ahlrichs, R ;

Fenske, D ;

McPartlin, M ;

Rothenberger, A ;

Schrodt, C ;

Wieber, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (25) :3932-3936

[2] Modeling the proposed intermediate in alkane carbon-hydrogen bond activation by Cp*(PMe3)Ir(Me)OTf:: Synthesis and stability of novel organometallic iridium(V) complexes [J].

Alaimo, PJ ;

Bergman, RG .

ORGANOMETALLICS, 1999, 18 (14) :2707-2717

[3]

ALKHATIB M, 2003, T MET CHEM, V28, P85

[4] Crystal structure of [Me3Sb-SbMe2]2[(MeSbBr3)2], a trimethylstibine adduct of the dimethylstibenium ion or a stibinostibonium salt? [J].

Althaus, H ;

Breunig, HJ ;

Lork, E .

CHEMICAL COMMUNICATIONS, 1999, (19) :1971-1972

[5] Mechanistic elucidation of the substitution behavior of alkyl cobaloximes in water and methanol as solvents [J].

Alzoubi, BM ;

Liehr, G ;

van Eldik, R .

INORGANIC CHEMISTRY, 2004, 43 (19) :6093-6100

[6] CHEMISTRY AT DIPLATINUM CENTERS [J].

ANDERSON, GK .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 35, 1993, 35 :1-39

[7] Ruthenium hydrides bearing SbPh3 and AsPh3 ligands:: characterization of the bis(dihydrogen) complexes [Cp*Ru(H2)2(EPh3)]+ (Cp* = C5Me5; E = Sb, As) [J].

Aneetha, H ;

Tenorio, MJ ;

Puerta, MC ;

Valerga, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 663 (1-2) :151-157

[8] SYNTHESIS, AND F-19 NMR AND X-RAY STRUCTURAL STUDIES OF TRIOSMIUM CLUSTERS (MU-H)OS3(CO)10L[ON(CF3)2](L=PPH3, ASPH3 AND SBPH3) [J].

ANG, HG ;

KOH, CH ;

KOH, LL ;

KWIK, WL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 452 (1-2) :181-184

[9] A new route to metal-halogen bond formation in metal carbonyl clusters:: crystal structure of the fluorinated cluster (μ-H)Os3(CO)10(AsPh3)F [J].

Ang, HG ;

Ang, SG ;

Leong, WY ;

Winfield, J .

JOURNAL OF FLUORINE CHEMISTRY, 1998, 88 (01) :5-8

[10] REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3H(MU-H)(CO)10(MPH3)] (M=P, AS, SB) - SYNTHESIS AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)10(PPH3)(ONC6F4O)] [J].

ANG, HG ;

KWIK, WL ;

ONG, KK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 474 (1-2) :149-152

← 1 2 3 4 5 6 7 8 9 10 →