Gold nanoparticle synthesis in worm-like catanionic micelles: microstructure conservation and temperature induced recovery

被引：32

作者：

Abecassis, Benjamin ^{[1
]}

Testard, Fabienne ^{[1
]}

Zemb, Thomas ^{[1
,2
]}

机构：

[1] LIONS, SCM, IRAMIS, CEA, F-91191 Gif Sur Yvette, France

[2] ENSCM, CNRS, CEA CNRS UM2, Inst Chim Separat Marcoule,UMR5257, F-30207 Bagnols Sur Ceze, France

来源：

SOFT MATTER | 2009年 / 5卷 / 05期

关键词：

IN-OIL MICROEMULSIONS; X-RAY-SCATTERING; REVERSE MICELLES; SURFACTANT; GROWTH; SITU; SUPERSTRUCTURES; NANOMATERIALS; NANOCRYSTALS; MOLECULES;

D O I：

10.1039/b816427d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spherical gold nanoparticles are synthesized in worm-like catanionic reverse micelles, demonstrating the absence of shape templating except when the growth of the particles is slow. In situ time resolved SAXS measurements show that the microstructure of the microemulsion is conserved during the whole reaction. The liquid-liquid phase transition of the catanionic microemulsion induced by a gentle cooling is used to recover and purify the nanoparticles in a simple manner.

引用

页码：974 / 978

页数：5

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