A supramolecular photocatalyst for the production of hydrogen and the selective hydrogenation of tolane

被引：307

作者：

Rau, Sven

Schaefer, Bernhard

Gleich, Dieter

Anders, Ernst

Rudolph, Manfred

Friedrich, Manfred

Goerls, Hehnar

Henry, Williani

Vos, Johannes G.

机构：

[1] Univ Jena, IAAC, D-07743 Jena, Germany

[2] Univ Jena, IOMC, D-07743 Jena, Germany

[3] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 37期

关键词：

homogeneous catalysis hydrogen; palladium; ruthenium; supramolecular chemistry;

D O I：

10.1002/anie.200600543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Light-driven metallo-organic catalysis: Intramolecular photoelectron transfer in the heterodinuclear complex 1 facilitates the photocatalytic production of hydrogen and the selective hydrogenation of tolane to give cis-stilbene. All three well-coordinated parts of the supramolecular system are essential: the (tbbpy)2Ru fragment as a photoactive unit, the redox-active bridging ligand as an electron relay and storage site, and the palladium as a catalytically active center. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：6215 / 6218

页数：4

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