Copper(I) 3-methylsalicylate, an efficient catalyst for N-arylation of heterocycles under moderate reaction conditions

被引：16
|
作者：
Farahat, Abdelbasset A. [1 ,2 ]
Boykin, David W. [1 ]
机构：
[1] Georgia State Univ, Dept Chem, Atlanta, GA 30303 USA
[2] Mansoura Univ, Fac Pharm, Dept Organ Pharmaceut Chem, Mansoura 35516, Egypt
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 19期
关键词：
Ullmann type coupling; Copper(I) 3-methylsalicylate; N-arylation; C-N bond formation; CROSS-COUPLING REACTIONS; C-N; ARYL BROMIDES; IODIDES;
D O I：
10.1016/j.tetlet.2014.03.117
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper(I) 3-methylsalicylate mediates N-arylation reactions of both aliphatic and aromatic heterocycles under moderate reaction conditions. Both electron rich and electron poor aryl bromides and a diverse set of N-heterocycles were allowed to react and gave N-arylation products in high yields which demonstrated the efficiency and utility of this catalyst. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3049 / 3051
页数：3
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