Can non-polar hydrogen atoms accept hydrogen bonds?

被引：14
|
作者：
Yang, Lixu [1 ]
Hubbard, Thomas A. [1 ]
Cockroft, Scott L. [1 ]
机构：
[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 40期
基金：
英国工程与自然科学研究理事会;
关键词：
MOLECULAR RECOGNITION; DISPERSION FORCES; FLUORINE; ALCOHOLS; ANION; ACIDS;
D O I：
10.1039/c3cc46048g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We examine an unusual case where a neutral hydrogen atom acts as a hydrogen-bond acceptor. The association constant between trihexylsilane and perfluoro-tert-butanol was measured as similar to 0.8 M-1 in cyclo-hexane. Computations and experimental NMR data are consistent with a weak, but favourable Si-H . . . HO interaction.
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页码：5212 / 5214
页数：3
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