An unusual o-metallated pyridyl dirhodium(II) complex:: [Rh2{μ-(C5H3N)NH(C5H4N)}2{η2-(C5H4N)NH(C5H4N}2]Cl2•CH3OH

被引：0
|
作者：
Cotton, FA
Murillo, CA
Stiriba, SE
机构：
[1] Texas A&M Univ, Dept Chem, Mol Struct & Bonding Lab, College Stn, TX 77842 USA
[2] Univ Costa Rica, Dept Quim, San Jose, Costa Rica
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 10期
关键词：
dirhodium compounds; orthometallation; pyridyl amine; crystal structures;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of Rb-2(O2CMe)(4) and bis(2-pyridyl)amine, Hdpa, followed by addition of CH2Cl2 led to replacement of the acetate groups by Hdpa and orthometallation of two Hdpa pyridyl groups. The isolated complex, [Rh-2{mu-(C5H3N)NH(C5H3N)}(2)(eta(2)-(C5H4N)NH(C5H4N}(2)]Cl-2 (1), has been characterized by X-ray crystallography, showing that the complex has two equatorially bound Hdpa groups and two bridging orthometallated dpa anions. (C) 1999 Elsevier Science S.A. All rights reserved.
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页码：463 / 464
页数：2
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