Molecular unit based on metal phthalocyanine; designed for molecular electronics

被引：1
|
作者：
Matsuda, M [1 ]
Hanasaki, N
Ikeda, S
Tajima, H
Naito, T
Inabe, T
机构：
[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[2] Hokkaido Univ, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan
来源：
JOURNAL DE PHYSIQUE IV | 2004年 / 114卷
关键词：
molecular electronics; phthalocyanine; pi-d system; thin film;
D O I：
10.1051/jp4:2004114128
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
We obtained three conducting crystals based on a [Fe-III(Pc)(CN)(2)] molecular unit. All crystals showed a large anisotropic negative magnetoresistance arising from the pi-d interaction self-contained in the [Fe-III(Pc)(CN)(2)] unit. The anisotropy is attributable to the anisotropic g-tensor in the [Fe-III(Pc)(CN)(2)] unit. We also obtained a thin film containing [Fe-III(Pc)(CN)(2)]. The film exhibits photocurrent response for the UV irradiation. These features suggest [M(Pc)(CN)(2)] molecular unit is a well-designed one for a building block of molecular devices.
引用
收藏
页码：541 / 543
页数：3
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