Synthesis of 8-alkoxy and 8,8′-dialkoxy derivatives of cobalt bis(dicarbollide)

被引：16

作者：

Stogniy, Marina Yu. ^{[1
]}

Suponitsky, Kyrill Yu. ^{[1
]}

Chizhov, Alexander O. ^{[2
]}

Sivaev, Igor B. ^{[1
]}

Bregadze, Vladimir I. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia

[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Leninsky Prosp 47, Moscow 119991, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 865卷

基金：

俄罗斯科学基金会;

关键词：

Cobalt bis(dicarbollide); Alkoxy derivatives; Synthesis; X-ray structure; ALKOXY DERIVATIVES; MOLECULAR-STRUCTURE; ION; ZWITTERION; CHEMISTRY;

D O I：

10.1016/j.jorganchem.2018.03.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, a simple and convenient way for synthesis of common alkoxy derivatives of cobalt bis(-dicarbollide) was developed and a series of 8-alkoxy [8-RO-3,3'-Co(1,2-C2B9H10)(1,2-C2B9H10)(1,2-C2B9H11)](-), 8-alkoxy-8'-hydroxy [8-RO-8'-HO-3.3'-Co(1,2-C2B9H10)(2)](-) and 8,8'-dialkoxy derivatives [8,8'-(RO)(2)-3,3'-Co(1,2-C2B9H10)(2)](-) (R = Me, Et, Pr) were synthesized. The solid state structure of (Me4N)[8,8'-(MeO)(2)-3,3'-Co(1,2-C2B9H10)(2)] was determined by single crystal X-ray diffraction study. (C) 2018 Elsevier B.V. All rights reserved.

引用

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页码：138 / 144

页数：7

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