The Zn-Rich Corner of the Zn-Al-Co-Sb Quaternary System at 450 and 600°C

被引：1

作者：

Wu, Da ^{[1
,2
]}

Zhu, Zhongxi ^{[1
,2
]}

Ma, Wenbo ^{[3
]}

Pan, Denghui ^{[1
,2
]}

Yin, Fucheng ^{[1
,2
]}

机构：

[1] Key Lab Mat Design & Preparat Technol Hunan Prov, Xiangtan, Hunan, Peoples R China

[2] Xiangtan Univ, Sch Mech Engn, Xiangtan 411105, Hunan, Peoples R China

[3] Xiangtan Univ, Coll Civil Engn & Mech, Xiangtan, Hunan, Peoples R China

来源：

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION | 2019年 / 40卷 / 03期

基金：

中国国家自然科学基金; 湖南省自然科学基金;

关键词：

galvanizing; phase diagram; scanning electron microscopy; x-ray diffraction; Zn-Al-Co-Sb quaternary system; TERNARY-SYSTEM; PHASE;

D O I：

10.1007/s11669-019-00730-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phase relations of the Zn-Al-Co-Sb quaternary system at 450 and 600 degrees C with Zn fixed at 93 at.% have been determined experimentally by means of scanning electron microscopy coupled with energy dispersive x-ray spectroscopy and x-ray diffraction. Four four-phase regions and three four-phase regions have been confirmed in these isothermal sections at 450 and 600 degrees C, respectively. The maximum solubilities of Zn in AlCo, Al5Co2 and Al13Co4 are 4.89, 18.98 and 7.85 at.%, respectively. Furthermore, no new ternary and quaternary compounds have been detected in this study.

引用

页码：356 / 363

页数：8

共 24 条

[1] ELECTRICAL AND OPTICAL PROPERTIES OF INTERMETALLIC COMPOUNDS .3. ALUMINUM ANTIMONIDE [J].

BLUNT, RF ;

FREDERIKSE, HPR ;

BECKER, JH ;

HOSLER, WR .

PHYSICAL REVIEW, 1954, 96 (03) :578-580

[2]

Bokii GB, 1965, ZH STRUKT KHIM, V6, P830

[3] STRUCTURE OF ZETA-PHASE IN TRANSITION METAL-ZINC ALLOY SYSTEMS [J].

BROWN, PJ .

ACTA CRYSTALLOGRAPHICA, 1962, 15 (JUN) :608-&

[4]

Chang S., 1995, GALV 95 C P CHIC ILL, P783

[5] Effect of galvanising parameters on spangle size investigated by data mining technique [J].

Dutta, M ;

Mukhopadhyay, A ;

Chakrabarti, S .

ISIJ INTERNATIONAL, 2004, 44 (01) :129-138

[6]

Godecke T, 1996, Z METALLKD, V87, P854

[7] REACTIVITY OF SILICON STEELS IN HOT-DIP GALVANIZING [J].

GUTTMAN, H ;

NIESSEN, P .

CANADIAN METALLURGICAL QUARTERLY, 1972, 11 (04) :609-615

[8] The isothermal section at 800 °C and an AlSb-Zn quasi-binary cut in the Al-Sb-Zn system [J].

Klancnik, Grega ;

Medved, Jozef .

COMPUTATIONAL MATERIALS SCIENCE, 2013, 66 :14-19

[9]

Li Fa-guo, 2010, Chinese Journal of Nonferrous Metals, V20, P86

[10] Structure of δ1-CoZn7.8, an example of a phason pinning-unpinning transformation? [J].

Lind, H ;

Boström, M ;

Petrícek, V ;

Lidin, S .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2003, 59 :720-729

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