Shaping the Synthesis and Assembly of Symmetrically Stellated Au/Pd Nanocrystals with Aromatic Additives

被引：16

作者：

DeSantis, Christopher J. ^{[1
]}

Sue, Aaron C. ^{[1
]}

Radmilovic, Andjela ^{[1
]}

Liu, Haoming ^{[1
]}

Losovyj, Yaroslav B. ^{[1
]}

Skrabalak, Sara E. ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

NANO LETTERS | 2014年 / 14卷 / 07期

基金：

美国国家科学基金会;

关键词：

Anisotropy; self-assembly; aromatic additives; supercrystals; branched; GOLD NANORODS;

D O I：

10.1021/nl501802u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Au/Pd octopods were synthesized with enhanced sample homogeneity through the use of aromatic additives. This increase in sample monodispersity facilitates large-area periodic assembly of stellated metal nanostructures for the first time. The aromatic additives were also found to influence the structures of the stellated nanocrystals with subtle shape modifications observed that can alter the packing arrangement of the Au/Pd octopods. These results indicate the possibility of tailored assembly of stellated nanostructures, which would be useful for optical applications that require strong and predictable coupling between plasmonic building blocks.

引用

页码：4145 / 4150

页数：6

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