Design and investigation of hydriding alloy based hydrogen storage reactor integrated with a pin fin tube heat exchanger

被引:47
作者
Keshari, Vikas [1 ]
Maiya, M. P. [1 ]
机构
[1] Indian Inst Technol, Refrigerat & Air Conditioning Lab, Dept Mech Engn, Madras 600036, Tamil Nadu, India
关键词
Metal hydride; Heat and mass transfer; Pin fin tube heat exchanger; Total absorption time; Simulation; MASS-TRANSFER; METAL; BED; DEVICE; OPTIMIZATION; SIMULATION; PERFORMANCE; PRESSURE; ETHANOL; SYSTEMS;
D O I
10.1016/j.ijhydene.2018.02.100
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reaction between metal hydride (MH) and hydrogen gas generates substantial amount of heat. It must be removed rapidly to sustain the reaction in the metal hydride hydrogen storage reactor. Previous studies indicate that the performance of the reactor can be improved by inserting an efficient heat exchanger design inside the metal hydride bed. In the present study, a cylindrical shaped metal hydride system containing LaNi5, integrated with a finned tube heat exchanger assembly made of copper pin fins and tubes, is presented. A 3-D numerical model is formulated in COMSOL Multiphysics 4.4 to study the transient behavior of sorption process inside the reactor. Experimental data obtained from the literature is used to approve the legitimacy of the proposed model. Influence of various operating and geometric parameters on the total absorption time of the reactor has been investigated. It is found that hydrogen supply pressure is the most influencing factor to increase the absorption rate of hydrogen. Total absorption time of the reactor is found to be 636 s with maximum storage capacity of 1.4 wt% at the operating conditions of 15 bar H-2 gas supply pressure, heat transfer fluid temperature of 298 K and flow rate of 6.75 l/min. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7081 / 7095
页数:15
相关论文
共 26 条
  • [1] Prediction of transient heat and mass transfer in a closed metal-hydrogen reactor
    Askri, F
    Jemni, A
    Ben Nasrallah, S
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (02) : 195 - 208
  • [2] Improvement of thermal performance of spiral heat exchanger on hydrogen storage by adding copper fins
    Dhaou, H.
    Ben Khedher, N.
    Mellouli, S.
    Souahlia, A.
    Askri, F.
    Jemni, A.
    Ben Nasrallah, S.
    [J]. INTERNATIONAL JOURNAL OF THERMAL SCIENCES, 2011, 50 (12) : 2536 - 2542
  • [3] Experimental study of a metal hydride vessel based on a finned spiral heat exchanger
    Dhaou, H.
    Souahlia, A.
    Mellouli, S.
    Askri, F.
    Jemni, A.
    Ben Nasrallah, S.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (04) : 1674 - 1680
  • [4] Pure hydrogen production via autothermal reforming of ethanol in a fluidized bed membrane reactor: A simulation study
    Gallucci, Fausto
    Annaland, Martin Van Sint
    Kuipers, J. A. M.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (04) : 1659 - 1668
  • [5] Optimization of internal heat exchangers for hydrogen storage tanks utilizing metal hydrides
    Garrison, Stephen L.
    Hardy, Bruce J.
    Gorbounov, Mikhail B.
    Tamburello, David A.
    Corgnale, Claudio
    vanHassel, Bart A.
    Mosher, Daniel A.
    Anton, Donald L.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (03) : 2850 - 2861
  • [6] Hydrogen cycling induced degradation in LaNi5-type materials
    Joubert, JM
    Latroche, M
    Cerny, R
    Percheron-Guégan, A
    Yvon, K
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 330 : 208 - 214
  • [7] Experimental analysis of fast metal hydride reaction bed dynamics
    Linder, Marc
    Mertz, Rainer
    Laurien, Eckart
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (16) : 8755 - 8761
  • [8] Advanced m-CHP fuel cell system based on a novel bio-ethanol fluidized bed membrane reformer
    Luis Viviente, Jose
    Melendez, Jon
    Pacheco Tanaka, David Alfredo
    Gallucci, Fausto
    Spallina, Vincenzo
    Manzolini, Giampaolo
    Foresti, Stefano
    Palma, Vincenzo
    Ruocco, Concetta
    Roses, Leonardo
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (19) : 13970 - 13987
  • [9] Optimization of heat transfer device and analysis of heat & mass transfer on the finned multi-tubular metal hydride tank
    Ma, Jincheng
    Wang, Yuqi
    Shi, Shaofei
    Yang, Fusheng
    Bao, Zewei
    Zhang, Zaoxiao
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (25) : 13583 - 13595
  • [10] Nuclear magnetic resonance studies of hydrogen diffusion in LaNi5.0H6.0 and LaNi4.8Sn0.2H5.8
    Majer, G
    Kaess, U
    Bowman, RC
    [J]. PHYSICAL REVIEW B, 1998, 57 (21): : 13599 - 13603