Polystyrene/calcium phosphate nanocomposites: Dynamic mechanical and differential scanning calorimetric studies

被引：42

作者：

Thomas, P. Selvin ^{[1
]}

Thomas, Sabu ^{[1
]}

Bandyopadhyay, Sri ^{[2
]}

Wurm, Andreas ^{[3
]}

Schick, Christoph ^{[3
]}

机构：

[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India

[2] Univ New S Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia

[3] Univ Rostock, Dept Phys, Rostock, Germany

来源：

COMPOSITES SCIENCE AND TECHNOLOGY | 2008年 / 68卷 / 15-16期

关键词：

Nanocomposites; Nanoparticles; Particle-reinforced composites; Differential scanning calorimetry (DSC); Dynamic mechanical thermal analysis (DMTA);

D O I：

10.1016/j.compscitech.2008.08.008

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

Calcium phosphate nanoparticles were prepared by the matrix mediated synthesis and were characterized using X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques. The particle size was found to be around 10 nm. Nanocomposites of polystyrene with calcium phosphate were prepared by melt mixing technique. Dynamic mechanical analysis and differential scanning calorimetric studies of the composites were performed. The storage modulus increased with respect to the filler loading and the glass transition temperature showed a positive shift indicating good reinforcement. The specific heat capacity measurements showed a drastic reduction, which indicated good filler matrix interaction. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：3220 / 3229

页数：10

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