The Current Status of Hydrogen Storage Alloy Development for Electrochemical Applications

被引：147
作者：
Young, Kwo-hsiung [1 ]
Nei, Jean [1 ]
机构：
[1] BASF Battery Mat Ovon, Rochester Hills, MI 48309 USA
来源：
MATERIALS | 2013年 / 6卷 / 10期
关键词：
metal hydride; hydrogen storage alloy; NiMH battery; alkaline fuel cell; electrochemical reaction; LAVES PHASE ALLOYS; METAL HYDRIDE ALLOY; COMPOSITION-TEMPERATURE HYSTERESIS; NEGATIVE ELECTRODE MATERIALS; ANNEALING TREATMENT; AS-CAST; MULTICOMPONENT ALLOYS; PARTIAL SUBSTITUTION; MAGNESIUM CONTENT; NICKEL-HYDROGEN;
D O I：
10.3390/ma6104574
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this review article, the fundamentals of electrochemical reactions involving metal hydrides are explained, followed by a report of recent progress in hydrogen storage alloys for electrochemical applications. The status of various alloy systems, including AB(5), AB(2), A(2)B(7)-type, Ti-Ni-based, Mg-Ni-based, BCC, and Zr-Ni-based metal hydride alloys, for their most important electrochemical application, the nickel metal hydride battery, is summarized. Other electrochemical applications, such as Ni-hydrogen, fuel cell, Li-ion battery, air-metal hydride, and hybrid battery systems, also have been mentioned.
引用
收藏
页码：4574 / 4608
页数：35
相关论文
共 235 条
[1]   Hydrogen absorption by Laves phase related BCC solid solution [J].
Akiba, E ;
Iba, H .
INTERMETALLICS, 1998, 6 (06) :461-470
[2]   ALLOYS FOR HYDROGEN STORAGE IN NICKEL-HYDROGEN AND NICKEL METAL HYDRIDE BATTERIES [J].
ANANI, A ;
VISINTIN, A ;
PETROV, K ;
SRINIVASAN, S ;
REILLY, JJ ;
JOHNSON, JR ;
SCHWARZ, RB ;
DESCH, PB .
JOURNAL OF POWER SOURCES, 1994, 47 (03) :261-275
[3]   Development of the high performance magnesium based hydrogen storage alloy [J].
Anik, Mustafa ;
Karanfil, Fatma ;
Kucukdeveci, Nilufer .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (01) :299-308
[4]   Improvement of the electrochemical hydrogen storage performance of magnesium based alloys by various additive elements [J].
Anik, Mustafa .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (02) :1905-1911
[5]   Effect of Titanium additive element on the discharging behavior of MgNi Alloy electrode [J].
Anik, Mustafa .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (23) :15075-15080
[6]   Electrochemical hydrogen storage characteristics of Mg-Pd-Ni ternary alloys [J].
Anik, Mustafa ;
Ozdemir, Gizem ;
Kucukdeveci, Nilufer .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (11) :6744-6750
[7]   Effect of Al, B, Ti and Zr additive elements on the electrochemical hydrogen storage performance of MgNi alloy [J].
Anik, Mustafa ;
Ozdemir, Gizem ;
Kucukdeveci, Nilufer ;
Baksan, Bedri .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (02) :1568-1577
[8]  
Ariga Y., 2003, J ALLOY COM IN PRESS
[9]  
Balogun M., 2012, J GUILIN U ELECT TEC, V32, P508
[10]   Effect of Al content on structure and electrochemical properties of LaNi4.4-xCo0.3Mn0.3Alx hydrogen storage alloys [J].
Balogun, Muhammad-Sadeeq ;
Wang, Zhong-min ;
Chen, He-xin ;
Deng, Jian-qiu ;
Yao, Qing-rong ;
Zhou, Huai-ying .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (25) :10926-10931
12345678910