Monolithic electrochemically promoted reactors:: A step for the practical utilization of electrochemical promotion

被引：22

作者：

Balomenou, S. P.

Tsiplakides, D.

Katsaounis, A.

Brosda, S.

Hammad, A.

Foti, G.

Comninellis, Ch.

Thiemann-Handler, S.

Cramer, B.

Vayenas, C. G. ^{[1
]}

机构：

[1] Univ Patras, Dept Chem Engn, GR-26504 Patras, Greece

[2] Ecole Polytech Fed Lausanne, Fac Basic Sci, CH-1015 Lausanne, Switzerland

[3] Robert Bosch GmbH, Corp Res & Dev, Stuttgart, Germany

来源：

SOLID STATE IONICS | 2006年 / 177卷 / 26-32期

关键词：

electrochemical promotion; monolithic electropromoted reactor; sputtered films;

D O I：

10.1016/j.ssi.2006.03.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel dismantlable monolithic-type electrochemically promoted catalytic reactor and "smart" sensor-catalytic reactor unit has been constructed and tested for hydrocarbon oxidation and NO reduction by C2H4 in the presence of O-2. In this novel reactor, thin (similar to 40 nm) porous catalyst films made of two different materials are sputter-deposited on opposing surfaces of thin (0.25 mm) parallel solid electrolyte plates supported in the grooves of a ceramic monolithic holder and serve as sensor or electropromoted catalyst elements. The catalyst dispersion was higher than 10%. A 22 flat plate reactor operated with apparent Faradaic efficiency up to 100, at near complete reactants conversion, at gas flow rates up to 30 l/min. The novel design has only two external electrical connections and thus significantly facilitates the practical utilization of electrochemical promotion of catalysis. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2201 / 2204

页数：4

共 21 条

[1] Novel monolithic electrochemically promoted catalytic reactor for environmentally important reactions [J].