Recent Progress in the Asymmetric Hydrosilylation of Ketones and Imines

被引：43

作者：

Arena, Carmela G. ^{[1
]}

机构：

[1] Univ Messina Salita Sperone, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2009年 / 6卷 / 03期

关键词：

Asymmetric catalysis; hydrosilylation; alcohols-amines; ketones; amines; EFFICIENT ENANTIOSELECTIVE HYDROSILYLATION; RHODIUM COMPLEXES; CATALYST SYSTEM; COPPER(I) SALT; REDUCTION; LIGANDS; HYDROGENATION; HYDROSILANE; ADDITIVES; CARBONYL;

D O I：

10.2174/157019309788922766

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric hydrosilylation of ketones and imines has seen significant advances in the last decade. The discovery of new highly efficient catalysts has turned this catalytic process into an attractive method for practical applications. Impressive chemical yields and enantioselectivities have been attained employing newly designed catalytic systems based on rhodium, copper, zinc and iron with suitable bidentate chiral ligands.

引用

收藏

页码：159 / 167

页数：9

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