Well-defined "clickable'' copolymers prepared via one-pot synthesis

被引：8

作者：

Ghasdian, Negar ^{[1
]}

Ward, Mark A. ^{[1
]}

Georgiou, Theoni K. ^{[2
]}

机构：

[1] Univ Hull, Dept Chem, Surfactant & Colloid Grp, Kingston Upon Hull HU6 7RX, N Humberside, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 54期

关键词：

AMPHIPHILIC MODEL CONETWORKS; COMBINATION; CHEMISTRY; POLYMERIZATION; METHACRYLATE; POLYMERS; BLOCK; FUNCTIONALIZATION; HYDROGELS; SEQUENCE;

D O I：

10.1039/c4cc02660h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Well-defined "clickable'' homo- and co-polymers were synthesised using a living polymerisation technique. Specifically propargyl methacrylate was successfully homo- and co-polymerised using group transfer polymerisation, GTP. This one-pot synthesis was performed without the need to protect the acetylenic group. Finally it was confirmed that the acetylenic functional group was unaffected by the polymerisation by clicking with azide 4-azidobenzoic acid.

引用

页码：7114 / 7116

页数：3

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