Perspective on "Theoretical interpretation of 1-2 asymmetric induction.: The importance of antiperiplanarity" -: !Anh NT, !Eisenstein O (1977) Nouv J Chim 1:61-70

被引：12

作者：

Houk, KN ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

THEORETICAL CHEMISTRY ACCOUNTS | 2000年 / 103卷 / 3-4期

关键词：

stereoselectivity; transition state; ab initio quantum mechanics;

D O I：

10.1007/s002149900037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper describes how Anh and Eisenstein's publication in 1977 solved a classic problem in organic stereochemistry and simultaneously provided the impetus and a model for the use of quantum mechanics to understand a wide range of organic chemical phenomena in a style accessible to experimental chemists.

引用

页码：330 / 331

页数：2

共 6 条

[1]

ANH NT, 1977, NOUV J CHIM, V1, P61

[2]

CIEPLAK AS, 1994, STRUCTURE CORRELATIO, V1, P205

[3]

Eliel E. L., 1994, STEREOCHEMISTRY ORGA, P875

[4] ABINITIO MECHANISMS FOR THE ADDITION OF CH3LI, HLI, AND THEIR DIMERS TO FORMALDEHYDE [J].

KAUFMANN, E ;

SCHLEYER, PV ;

HOUK, KN ;

WU, YD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (19) :5560-5562

[5] STAGGERED MODELS FOR ASYMMETRIC INDUCTION - ATTACK TRAJECTORIES AND CONFORMATIONS OF ALLYLIC BONDS FROM ABINITIO TRANSITION STRUCTURES OF ADDITION-REACTIONS [J].

PADDONROW, MN ;

RONDAN, NG ;

HOUK, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7162-7166

[6] EFFECT OF TORSIONAL STRAIN AND ELECTROSTATIC INTERACTIONS ON THE STEREOCHEMISTRY OF NUCLEOPHILIC ADDITIONS TO CYCLOHEXANONE AND RELATED SYSTEMS [J].

WU, YD ;

HOUK, KN ;

PADDONROW, MN .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (08) :1019-1021

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