Perspective on "Theoretical interpretation of 1-2 asymmetric induction.: The importance of antiperiplanarity" -: !Anh NT, !Eisenstein O (1977) Nouv J Chim 1:61-70
被引:12
作者:
Houk, KN
论文数: 0引用数: 0
h-index: 0
机构:
Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USAUniv Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
Houk, KN
[1
]
机构:
[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
stereoselectivity;
transition state;
ab initio quantum mechanics;
D O I:
10.1007/s002149900037
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
This paper describes how Anh and Eisenstein's publication in 1977 solved a classic problem in organic stereochemistry and simultaneously provided the impetus and a model for the use of quantum mechanics to understand a wide range of organic chemical phenomena in a style accessible to experimental chemists.