Insights into the mechanism of methanol-to-olefin conversion at zeolites with systematically selected framework structures

被引：112

作者：

Cui, Zhi-Min ^{[1
]}

Liu, Qiang ^{[1
]}

Song, Wei-Guo ^{[1
]}

Wan, Li-Jun ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 39期

关键词：

heterogeneous catalysis; isotopic labeling; methanol-to-olefin process; reaction mechanisms; zeolites;

D O I：

10.1002/anie.200602488

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Com-paring mechanisms: The so-called hydrocarbon pool mechanism does not operate with zeolite ZSM-22 in the methanol-to-olefin (MTO) conversion process as a result of the narrow channels (0.57 nm) in its framework structure. However, this provided a condition free of secondary reactions for detailed mechanistic studies, with H/D exchange patterns of toluene suggesting a paring mechanism. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6512 / 6515

页数：4

共 29 条

[1] Theoretical study of the heptamethylbenzenium ion. Intramolecular isomerizations and C2, C3, C4 alkene elimination
Arstad, B
Kolboe, S
Swang, O
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (39) : 8914 - 8922
[2] The reactivity of molecules trapped within the SAPO-34 cavities in the methanol-to-hydrocarbons reaction
Arstad, B
Kolboe, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) : 8137 - 8138
[3] Conversion of methanol to hydrocarbons: the reactions of the heptamethylbenzenium cation over zeolite H-beta
Bjorgen, M
Olsbye, U
Svelle, S
Kolboe, S
[J]. CATALYSIS LETTERS, 2004, 93 (1-2) : 37 - 40
[4] CONVERSION OF METHANOL AND OTHER O-COMPOUNDS TO HYDROCARBONS OVER ZEOLITE CATALYSTS
CHANG, CD
SILVESTRI, AJ
[J]. JOURNAL OF CATALYSIS, 1977, 47 (02) : 249 - 259
[5] ON THE REACTION-MECHANISM FOR PROPENE FORMATION IN THE MTO REACTION OVER SAPO-34
DAHL, IM
KOLBOE, S
[J]. CATALYSIS LETTERS, 1993, 20 (3-4) : 329 - 336
[6] Confinement effects in the adsorption of simple bases by zeolites
Derouane, EG
Chang, CD
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 35-6 : 425 - 433
[7] Roles for cyclopentenyl cations in the synthesis of hydrocarbons from methanol on zeolite catalyst HZSM-5
Haw, JF
Nicholas, JB
Song, WG
Deng, F
Wang, ZK
Xu, T
Heneghan, CS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (19) : 4763 - 4775
[8] Well-defined (supra)molecular structures in zeolite methanol-to-olefin catalysis
Haw, JF
Marcus, DM
[J]. TOPICS IN CATALYSIS, 2005, 34 (1-4) : 41 - 48
[9] The mechanism of methanol to hydrocarbon catalysis
Haw, JF
Song, WG
Marcus, DM
Nicholas, JB
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (05) : 317 - 326
[10] Applications of in situ spectroscopy in zeolite catalysis
Hunger, M
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 82 (03) : 241 - 255

← 1 2 3 →