Insights into the mechanism of methanol-to-olefin conversion at zeolites with systematically selected framework structures

被引：112

作者：

Cui, Zhi-Min ^{[1
]}

Liu, Qiang ^{[1
]}

Song, Wei-Guo ^{[1
]}

Wan, Li-Jun ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 39期

关键词：

heterogeneous catalysis; isotopic labeling; methanol-to-olefin process; reaction mechanisms; zeolites;

D O I：

10.1002/anie.200602488

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Com-paring mechanisms: The so-called hydrocarbon pool mechanism does not operate with zeolite ZSM-22 in the methanol-to-olefin (MTO) conversion process as a result of the narrow channels (0.57 nm) in its framework structure. However, this provided a condition free of secondary reactions for detailed mechanistic studies, with H/D exchange patterns of toluene suggesting a paring mechanism. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6512 / 6515

页数：4

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