Mechanism of hexafluoropropylene formation in gas-phase pyrolysis of tetrafluoroethylene

被引：8

作者：

Buravtsev, NN ^{[1
]}

Kolbanovskii, YA ^{[1
]}

机构：

[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2002年 / 75卷 / 04期

关键词：

D O I：

10.1023/A:1019521231578

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The consecutive formation of short-lived intermediates during tetrafluoroethylene conversion into hexafluoropropylene by gas-phase pyrolysis under conditions of pulsed adiabatic compression was studied by kinetic spectroscopy. The process mechanism was determined in detail. The ways for improving the pyrolysis procedure were considered.

引用

页码：598 / 605

页数：8

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