Mechanism of hexafluoropropylene formation in gas-phase pyrolysis of tetrafluoroethylene

被引：8
作者：
Buravtsev, NN [1 ]
Kolbanovskii, YA [1 ]
机构：
[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2002年 / 75卷 / 04期
关键词：
D O I：
10.1023/A:1019521231578
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The consecutive formation of short-lived intermediates during tetrafluoroethylene conversion into hexafluoropropylene by gas-phase pyrolysis under conditions of pulsed adiabatic compression was studied by kinetic spectroscopy. The process mechanism was determined in detail. The ways for improving the pyrolysis procedure were considered.
引用
收藏
页码：598 / 605
页数：8
相关论文
共 64 条
[1]  
AINAGOS AF, 1991, KINET CATAL+, V32, P720
[2]   THERMAL DECOMPOSITION OF PERFLUOROCYCLOPROPANE [J].
ATKINSON, B ;
MCKEAGAN, D .
CHEMICAL COMMUNICATIONS, 1966, (07) :189-&
[3]   KINETICS OF DISSOCIATION AND ISOMERISATION OF HEXAFLUORO-1,2-BIS-TRIFLUOROMETHYLCYCLOBUTANE [J].
ATKINSON, B ;
STOCKWELL, PB .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (10) :984-+
[4]   DETERMINATION OF THE HEAT OF DIMERIZATION OF TETRAFLUOROETHYLENE BY A KINETIC METHOD [J].
ATKINSON, B ;
TRENWITH, AB .
JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (04) :754-755
[5]   KINETICS OF CYCLODIMERIZATION OF HEXAFLUOROPROPENE AND OF ITS CYCLO-ADDITION TO CHLOROTRIFLUOROETHENE [J].
ATKINSON, B ;
TSIAMIS, C .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1979, 11 (10) :1029-1043
[6]   THE THERMAL DECOMPOSITION OF TETRAFLUORETHYLENE [J].
ATKINSON, B ;
TRENWITH, AB .
JOURNAL OF THE CHEMICAL SOCIETY, 1953, (JUL) :2082-2087
[7]   THE THERMAL DECOMPOSITION OF TETRAFLUOROETHYLENE [J].
ATKINSON, B ;
ATKINSON, VA .
JOURNAL OF THE CHEMICAL SOCIETY, 1957, (MAY) :2086-2094
[8]  
Barltrop J.A., 1975, EXCITED STATES ORGAN
[9]  
Bauer SH, 1998, INT J CHEM KINET, V30, P171, DOI 10.1002/(SICI)1097-4601(1998)30:3<171::AID-KIN1>3.0.CO
[10]  
2-P
1234567