A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO2

被引：61

作者：

Burgun, Alexandre ^{[1
]}

Crees, Rachel S. ^{[1
]}

Cole, Marcus L. ^{[2
]}

Doonan, Christian J. ^{[1
]}

Sumby, Christopher J. ^{[1
]}

机构：

[1] Univ Adelaide, Sch Chem & Phys, Adelaide, SA, Australia

[2] Univ New S Wales, Sch Chem, Sydney, NSW, Australia

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 79期

基金：

澳大利亚研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; BUILDING UNITS; IMIDAZOLIUM DICARBOXYLATE; HYDROSILYLATION REACTIONS; COPPER COMPLEXES; HYDROGEN STORAGE; CARBON-DIOXIDE; CATENATION; CLUSTERS; WATER;

D O I：

10.1039/c4cc04761c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new MOF, [Zn4O{Cu(L)(2)}(2)] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L)(2)] NHC linkers. MOF 1 possesses tetrahedral Zn4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L)(2)] linkers, and 14 angstrom 1-D pore channels lined with [Cu(L)(2)] moieties that catalyse the hydroboration of CO2.

引用

页码：11760 / 11763

页数：4

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