Hydrogenation of (Zr69.5Al7.5CU12Ni11)100-xTix quasicrystalline alloys and its effect on their structural and microhardness behavior

被引:9
作者
Singh, Devinder [1 ,2 ,3 ]
Shahi, Rohit R. [1 ,2 ]
Yadav, T. P. [1 ,2 ]
Mandal, R. K. [4 ]
Tiwari, R. S. [1 ,2 ]
Srivastava, O. N. [1 ,2 ]
机构
[1] Banaras Hindu Univ, Hydrogen Energy Ctr, Varanasi 221005, Uttar Pradesh, India
[2] Banaras Hindu Univ, Dept Phys, Unit Nanosci & Technol, Varanasi 221005, Uttar Pradesh, India
[3] Panjab Univ, Dept Phys, Chandigarh 160014, India
[4] Banaras Hindu Univ, Indian Inst Technol, Dept Met Engn, Varanasi 221005, Uttar Pradesh, India
关键词
Hydrogen storage; Nanoquasicrystal; Melt-spinning; Microstructure; Microhardness; METALLIC GLASSES; INDENTATION CHARACTERISTICS; MECHANICAL-PROPERTIES; TI ADDITION; PHASE; PD; NANOINDENTATION; COMPOSITE; STORAGE;
D O I
10.1016/j.jnoncrysol.2013.08.024
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The present study deals with the microstructural changes with respect to the addition of Ti and their correlation with hydrogen storage characteristics of (Zr69.5Al7.5Cu12Ni11)(100) (-) Ti-x(x) (x = 0,4 and 12) quasicrystalline alloys. The grain size of quasicrystals decreases with addition of Ti. It has been found that the alloy with x = 0 absorbed 1.20 wt.%, whereas the alloys with x = 4 and 12 absorbed 1.38 wt.% and 1.56 wt.% of hydrogen respectively. Hydrogenation was found to exhibit a significant effect on the structure/microstructure and microhardness behavior of (Zr69.5Al7.5Cu12Ni11)(100) - Ti-x (x) quasicrystalline alloys. Variation in the microhardness behavior has been discussed based on a structure-property correlation. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:11 / 16
页数:6
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