Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

被引：106

作者：

Manimaran, B

Thanasekaran, P

Rajendran, T

Lin, RJ

Chang, IJ

Lee, GH

Peng, SM

Rajagopal, S

Lu, KL ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Normal Univ, Dept Chem, Taipei 117, Taiwan

[3] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan

[4] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 21期

关键词：

D O I：

10.1021/ic020364n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of rhenium(l)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(l) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

引用

页码：5323 / 5325

页数：3

共 37 条

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