Synthesis and characterization of manganese(III) complexes of a chiral disulfonamide ligand based on trans-1,2-diaminocyclohexane

被引：0

作者：

Bernardo, K ^{[1
]}

Robert, A ^{[1
]}

Meunier, B ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

POLYHEDRON | 1997年 / 16卷 / 14期

关键词：

chiral; disulfonamide ligand; manganese(III); epoxidation; trans-1,2-diaminocyclohexane;

D O I：

10.1016/S0277-5387(96)00583-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of an optically active disulfonamide ligand based on trans-1,2-diaminocyclohexane as chiral motif is reported. The corresponding anionic manganese(III) complex has been evaluated as potential catalyst for enantioselective olefin epoxidations, and found to be inactive. (C) 1997 Elsevier Science Ltd.

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页码：2365 / 2368

页数：4

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